Hydroxyl-functionalized ionic liquid:: a novel efficient catalyst for chemical fixation of CO2 to cyclic carbonate

被引：364
|
作者：
Sun, Jian [1 ,2 ]
Zhang, Suojiang [1 ]
Cheng, Weiguo [1 ]
Ren, Junyi [3 ]
机构：
[1] Chinese Acad Sci, Inst Proc Engn, State Key Multiphase Complex Syst, Beijing 100190, Peoples R China
[2] Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Dalian Polytech Univ, Dalian 116034, Peoples R China
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 22期
基金：
中国国家自然科学基金;
关键词：
ionic liquid; carbon dioxide; chemical fixation; cyclic carbonate;
D O I：
10.1016/j.tetlet.2008.04.022
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of hydroxyl-functionalized ionic liquids (HFILs) were synthesized and characterized. They showed efficient reactivity and reusability toward the coupling of epoxide and CO2 without any additional co-catalyst and organic solvent. Highest activity and selectivity were achieved in the presence of 1-(2-hydroxyl-ethyl)-3-methylimidazolium bromide (HEMIMB) in comparison with other similar catalysts investigated. The relationship between the higher catalytic reactivity and OH-functional group was proposed. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3588 / 3591
页数：4
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