α-chlorovinylation:: Synthesis of 2-chloropropenyl and propargyl alcohols

被引：15
|
作者：
Falck, JR [1 ]
Barma, DK
Mioskowski, C
Schlama, T
机构：
[1] Univ Texas, SW Med Ctr, Dept Biochem, Dallas, TX 75235 USA
[2] Univ Texas, SW Med Ctr, Dept Pharmacol, Dallas, TX 75235 USA
[3] Univ Strasbourg 1, Fac Pharm, CNRS, Lab Synth Bioorgan, F-67401 Illkirch Graffenstaden, France
来源：
TETRAHEDRON LETTERS | 1999年 / 40卷 / 11期
关键词：
alcohols; alkenyl halides; alkynes; chromium;
D O I：
10.1016/S0040-4039(99)00153-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Formal alpha-chlorovinylation of aldehydes using CH3CCl3/CrCl2 affords 2-chloropropenyl alcohols from which terminal propargyl alcohols are obtained via base Induced elimination. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2091 / 2094
页数：4
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