Tetrakis[pyridine-2(1H)-thione-κS]platinum(II) dichloride

被引：8
|
作者：
Mizota, M
Yokoyama, Y
Sakai, K
机构：
[1] Kyushu Univ, Fac Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan
[2] Sci Univ Tokyo, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词：
D O I：
10.1107/S1600536805020209
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Pt(C5H5NS)(4)]Cl-2, the Pt-II ion is located at a crystallographic inversion centre, with each S-donor ligand in its thione tautomeric form [Pt-S = 2.3439 ( 7) and 2.3444 ( 7)angstrom]. The Cl- ion positioned at each axial site of the Pt-II ion [(PtCl)-Cl-... = 3.5171 (8) angstrom] is hydrogen-bonded to the N-H units of the ligands [(ClN)-N-... = 3.103 (3) and 3.125 ( 3) angstrom].
引用
收藏
页码：M1433 / M1435
页数：3
相关论文
共 50 条
  • [31] On the homolytic cleavage of the N,O bond in N-(methoxy)pyridine-2(1H)-thione and N-(methoxy)thiazole-2(3H)-thione in thermally and photochemically induced reactions:: A theoretical study
    Arnone, M
    Hartung, J
    Engels, B
    JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (26): : 5943 - 5950
  • [32] Synthesis of 4,5-dipyridylpyridin-2(1H)-ones, pyridine-2(1H)-thiones and related derivatives as analoges of cardiotonic drug milrinone
    Krauze, A
    Garalene, V
    Vitolina, R
    Duburs, G
    HETEROCYCLIC COMMUNICATIONS, 2001, 7 (05) : 427 - 432
  • [33] Ionization behaviour and tautomerism-dependent lipophilicity of pyridine-2(1H)-one cardiotonic agents
    Altomare, C
    Cellamare, S
    Summo, L
    Fossa, P
    Mosti, L
    Carotti, A
    BIOORGANIC & MEDICINAL CHEMISTRY, 2000, 8 (05) : 909 - 916
  • [34] NOVEL SYNTHESIS OF PYRIDINE-2(1H)THIONES, N-AMINO-2-PYRIDONES AND PYRIDAZINE DERIVATIVES
    ELGEMEIE, GH
    ELEZBAWY, SR
    RAMIZ, MM
    MANSOUR, OA
    ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1991, 23 (05) : 645 - 650
  • [35] 6-Methylpyridine-2(1H)-thione
    Lian, Guo-Jun
    Chen, Bo
    Zhang, Ting-Ting
    Zhuang, Li-Zhen
    Liang, Hong-Ze
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1154 - U791
  • [36] 2 PYRIDINE-2,6(1H,3H)-DIONE ALKALOIDS FROM SPERANSKIA-TUBERCULATA
    SHI, JG
    WANG, HQ
    WANG, M
    ZHU, Y
    PHYTOCHEMISTRY, 1995, 40 (04) : 1299 - 1302
  • [37] PREPARATION, CHARACTERIZATION AND CRYSTAL-STRUCTURE OF DICHLORO TETRAKIS-(1-METHYLIMIDAZOLINE-2(3H)-THIONE) PLATINUM(II) DIHYDERATE
    ONEILL, ME
    RAPER, ES
    DANIELS, JA
    NOWELL, IW
    INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1982, 66 (03): : 79 - 84
  • [38] Synthesis of 4-substituted pyridin-2(1H)-ones, pyridine-2(1H)-thiones, related derivatives as analogues of cardiotonic drug milrinone
    Krauze, A
    Vitolina, R
    Garalene, V
    Jänsch, HJ
    Duburs, G
    HETEROCYCLIC COMMUNICATIONS, 1999, 5 (06) : 569 - 576
  • [39] Complexes with S-donor ligands .4. Mono- and di-homo- and hetero-nuclear gold(I), silver(I), and palladium(II) complexes with 2-(methylthio)pyridine, pyridine-2(1H)-thione, and benzoxazole-2(3H)-thione. Some examples of the use of complexes as ligands
    Vicente, J
    Chicote, MT
    Rubio, C
    CHEMISCHE BERICHTE-RECUEIL, 1996, 129 (03): : 327 - 330
  • [40] Chemical and Electrochemical Preparation for Co(II) Complexes of Some Novel Pyridine-2-(1H)-Thione Ring Fused Cycloalkane Derivatives
    Amin, Ragab R.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (03) : 537 - 543
12345