NMR study of the stoichiometry and stability of complexation reaction between Mg2+, Ca2+, Sr2+ and Ba2+ ions and 60-crown-20 in binary acetonitrile solvent mixtures

被引：4

作者：

Rahimi-Nasrabadi, M. ^{[1
]}

Pourmohamadian, S. ^{[2
]}

Pourmortazavi, S. M. ^{[3
]}

Ahmadi, F. ^{[4
]}

Ganjali, M. R. ^{[5
]}

Moghimi, A. ^{[1
]}

机构：

[1] Imam Hossein Univ, Dept Chem, Tehran, Iran

[2] Islamic Azad Univ, Varamin Pishva Branch, Varamin, Iran

[3] Malek Ashtar Univ Technol, Fac Mat & Mfg Technol, Tehran, Iran

[4] Kermanshah Univ Med Sci, Fac Pharm, Dept Med Chem, Kermanshah, Iran

[5] Univ Tehran, Fac Chem, Tehran, Iran

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2012年 / 73卷 / 1-4期

关键词：

60-Crown-20; NMR; Mixed solvents; Complex formation constants; METAL-IONS; MACROCYCLE INTERACTION; KINETIC-DATA; POTASSIUM; TRANSPORT; SODIUM; LIGAND;

D O I：

10.1007/s10847-011-0051-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Proton nuclear magnetic resonance (H-1-NMR) spectroscopy was used to study the complexation reaction between Mg2+, Ca2+, Sr2+ and Ba2+ ions and 60-crown-20 in a series of binary mixtures of deuterated acetonitrile (AN), nitromethane (NM) and D2O at 27 A degrees C. Formation constants of the 1:1 complexes were determined through computer fitting of the chemical shift/mol ratio data and found to vary in the order of Ba2+ > Sr2+ > Mg2+ a parts per thousand Ca2+. The influence of the solvent composition on the stability of the resulting complexes was also discussed. In all cases, the changes in the stability constants with the solvent composition were monotonic and showed a good correlation with the inherent solvation ability of the pure solvents which form the mixture.

引用

页码：263 / 267

页数：5

共 50 条

[21] Effects of Na+ , Mg2+ , Ca2+ , Sr2+ and Ba2+ Doping on the Scintillation Properties of CeBr3
Awater, Roy H. P.
Kraemer, Karl. W.
Dorenbos, Pieter
IEEE TRANSACTIONS ON NUCLEAR SCIENCE, 2015, 62 (05) : 2343 - 2348
[22] Influence of various divalent impurities on dislocation density in KCl:Mg2+, Ca2+, Sr2+ or Ba2+ single crystals
Kohzuki, Y
JOURNAL OF MATERIALS SCIENCE, 2003, 38 (05) : 953 - 958
[23] MEAN ACTIVITY-COEFFICIENTS OF H+, MG2+, CA2+, SR2+ AND BA2+ IONS IN AQUEOUS-SOLUTIONS OF CORRESPONDING NITRATES
VALENZUELACALAHORRO, C
HERNANDEZALVARO, J
LOPEZGONZALEZ, JDD
ANALES DE QUIMICA, 1979, 75 (11): : 833 - 838
[24] Structure, solvation, and dynamics of Mg2+, Ca2+, Sr2+, and Ba2+ complexes with 3-hydroxyflavone and perchlorate anion in acetonitrile medium: A molecular dynamics simulation study
Agieienko, Vira N.
Kolesnik, Yaroslav V.
Kalugin, Oleg N.
JOURNAL OF CHEMICAL PHYSICS, 2014, 140 (19):
[25] Study of complex formation between dicyclohexano-18-crown-6 (DCH18C6) with Mg2+, Ca2+,Sr2+, and Ba2+ cations in methanol-water binary mixtures using conductometric method
Rounaghi, GH
Mofazzeli, F
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2005, 51 (3-4) : 205 - 210
[26] Effect of Ba2+ on the biomineralization of Ca2+ and Mg2+ ions induced by Bacillus licheniformis
Yan, Huaxiao
Zhu, Xiaofei
Li, Zhenjiang
Liu, Zhiyong
Jin, Shengping
Zhou, Xiaotong
Han, Zuozhen
Woo, Jusun
Meng, Long
Chi, Xiangqun
Han, Chao
Zhao, Yanyang
Tucker, Maurice E.
Zhao, Yueming
Zhao, Hui
Waheed, Junaid
WORLD JOURNAL OF MICROBIOLOGY & BIOTECHNOLOGY, 2024, 40 (06):
[27] EFFECTS OF METHOXYVERAPAMIL ON THE STIMULATION BY CA2+, SR2+ AND BA2+ AND ON THE INHIBITION BY MG2+ OF CATECHOLAMINE RELEASE FROM THE ADRENAL-MEDULLA
AGUIRRE, J
FALUTZ, J
PINTO, JEB
TRIFARO, JM
BRITISH JOURNAL OF PHARMACOLOGY, 1979, 66 (04) : 591 - 600
[28] FTIR study of low-temperature CO adsorption on Y zeolite exchanged with Be2+, Mg2+, Ca2+, Sr2+ and Ba2+ cations
Hadjiivanov, K
Ivanova, E
Knözinger, H
MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 58 (03) : 225 - 236
[29] Polythermal study of the systems M(ClO4)2-H2O(M2+ = Mg2+, Ca2+, Sr2+, Ba2+)
Pestova, ON
Myund, LA
Khripun, MK
Prigaro, AV
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2005, 78 (03) : 409 - 413
[30] Polythermal Study of the Systems M(ClO4)2-H2O (M2+ = Mg2+, Ca2+, Sr2+, Ba2+)
O. N. Pestova
L. A. Myund
M. K. Khripun
A. V. Prigaro
Russian Journal of Applied Chemistry, 2005, 78 : 409 - 413

← 1 2 3 4 5 →