Utilization of Formic Acid as C1 Building Block for the Ruthenium-Catalyzed Synthesis of Formaldehyde Surrogates

被引：13

作者：

Beydoun, Kassem ^{[1
]}

Thenert, Katharina ^{[1
]}

Wiesenthal, Jan ^{[1
]}

Hoppe, Corinna ^{[1
]}

Klankermayer, Juergen ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, Worringerweg 2, D-52074 Aachen, Germany

来源：

CHEMCATCHEM | 2020年 / 12卷 / 07期

关键词：

molecular catalysis; formic acid; formaldehyde; catalytic hydrogenation; sustainable chemistry; CARBON-DIOXIDE REDUCTION; HYDROGENATION; DIMETHOXYMETHANE; ETHERS; FUEL;

D O I：

10.1002/cctc.201902332

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dialkoxymethanes are becoming increasingly important as fuel additives, formaldehyde surrogates, and chemical intermediates, but the effective synthesis remains challenging. Herein, the catalytic synthesis of dialkoxymethane products using a molecular catalyst is reported. The catalytic system, comprising the [Ru(triphos)(tmm)] in combination with the Lewis acid Al(OTf)(3), enables the direct synthesis of dialkoxymethane products with formic acid as C1 building block in high to excellent turnover numbers.

引用

页码：1944 / 1947

页数：4

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