Identification of a precursor to naturally occurring β-damascenone

被引：24
|
作者：
Puglisi, CJ
Elsey, GM
Prager, RH
Skouroumounis, GK
Sefton, MA
机构：
[1] Australian Wine Res Inst, Glen Osmond, SA 5064, Australia
[2] Flinders Univ S Australia, Sch Chem Phys & Earth Sci, Adelaide, SA 5001, Australia
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 39期
关键词：
beta-damascenone; flavour precursors; wine; carotenoid metabolites;
D O I：
10.1016/S0040-4039(01)01411-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
9-Hydroxymegastigma-3,5-dien-7-yne 8a was synthesised and shown to be identical to an intermediate found in the acid-catalysed conversion of 3,5,9-trihydroxymegastigma-6,7-diene 4 to beta -damascenone 1, 3-hydroxydamascone 5 and megastigma-5-en-7-yne-3,9-diol 6. When subjected to acid hydrolysis, 8a produced beta -damascenone 1, in high yield. Importantly, the hydrolysate was completely free of 3-hydroxydamascone 5. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6937 / 6939
页数：3
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