Photorefractive effect of photoconductive ferroelectric liquid crystalline mixtures composed of photoconductive chiral compounds and liquid crystal

被引:31
|
作者
Sasaki, Takeo [1 ]
Miyazaki, Daisuke [1 ]
Akaike, Komei [1 ]
Ikegami, Masashi [1 ]
Naka, Yumiko [1 ]
机构
[1] Tokyo Univ Sci, Fac Sci, Dept Chem, Shinjuku Ku, Tokyo 1628601, Japan
基金
日本科学技术振兴机构;
关键词
PALLADIUM; POLYMER; LIGAND;
D O I
10.1039/c1jm10405e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photorefractive effect in photoconductive ferroelectric liquid crystals (FLCs) that contain photoconductive chiral compounds was investigated. A series of novel photoconductive chiral compounds were synthesized. Terthiophene compounds with four chiral structures were chosen as the photoconductive chiral compounds and mixed with an achiral smectic C liquid crystal. The mixtures exhibit the ferroelectric chiral smectic C phase. The photorefractivity of the mixtures was investigated by two-beam coupling experiments. It was found that the FLCs containing the photoconductive chiral compound exhibit a large gain coefficient of 110 cm(-1) and a fast response time of 5 ms.
引用
收藏
页码:8678 / 8686
页数:9
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