Valence tautomerism in a o-benzoquinone adduct of a tetraazamacrocycle complex of manganese

被引：0
|
作者：
Caneschi, A [1 ]
Dei, A [1 ]
机构：
[1] Univ Florence, Dipartimento Chim, I-50144 Florence, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 21期
关键词：
magnetic properties; manganese; O ligands; tautomerism;
D O I：
10.1002/(SICI)1521-3773(19981116)37:21<3005::AID-ANIE3005>3.0.CO;2-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two different charge distributions of the complex cation [Mn(III)(cth)(diox)]+ (cth = a tetraazamacrocycle, diox = 3,5-di-tert- butyl-o-benzoquinone; structure shown in the picture) can be isolated by varying the counteranion: [Mn(III)(cth)(cat)]BPh4 and [Mn(II)(cth)(sq)]ClO4 (cat and sq denote the catecholato and semiquinonato forms of the ligand). The complex undergoes noncooperative entropy-driven valence tautomeric transitions.
引用
收藏
页码：3005 / 3007
页数：3
相关论文
共 50 条
  • [41] Theoretical determination of the magnetic properties of 2-pyrone and 4-pyrone, and o-benzoquinone and p-benzoquinone
    Ligabue, A
    Lazzeretti, P
    MOLECULAR PHYSICS, 2003, 101 (16) : 2497 - 2509
  • [42] A Switchable Complex Ligand Exhibiting Photoinduced Valence Tautomerism
    Dai, Jingwei
    Kanegawa, Shinji
    Li, Zhaoyang
    Kang, Soonchul
    Sato, Osamu
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 2013 (24) : 4150 - 4153
  • [43] LIGAND-INDUCED VALENCE TAUTOMERISM IN MANGANESE-QUINONE COMPLEXES
    LYNCH, MW
    HENDRICKSON, DN
    FITZGERALD, BJ
    PIERPONT, CG
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (13) : 3961 - 3963
  • [44] o-Benzoquinone Cobalt Complexes Bearing Organosilicon Radicals: Quantum-Chemical Study
    A. A. Starikova
    M. G. Chegerev
    A. G. Starikov
    V. I. Minkin
    Russian Journal of Coordination Chemistry, 2022, 48 : 233 - 241
  • [45] 3, 6-Di(tert-butyl)-o-benzoquinone fluoroalkylated derivatives
    V. K. Cherkasov
    N. O. Druzhkov
    A. A. Zolotukhin
    A. S. Shavyrin
    E. N. Egorova
    Russian Chemical Bulletin, 2015, 64 : 2718 - 2724
  • [46] Valence-tautomerism in high-valent iron and manganese porphyrins
    Weiss, R
    Bulach, V
    Gold, A
    Terner, J
    Trautwein, AX
    JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2001, 6 (08): : 831 - 845
  • [47] Valence-tautomerism in high-valent iron and manganese porphyrins
    Raymond Weiss
    Véronique Bulach
    Avram Gold
    James Terner
    Alfred X. Trautwein
    JBIC Journal of Biological Inorganic Chemistry, 2001, 6 : 831 - 845
  • [48] Continuous In Situ Electrogeneration of o-Benzoquinone in Microreactor: Application to High Yield Reaction with Benzenethiols
    Tsuneo Kashiwagi
    Fumihiro Amemiya
    Toshio Fuchigami
    Mahito Atobe
    Journal of Flow Chemistry, 2013, 3 : 17 - 22
  • [49] 3,6-Di(tert-butyl)-o-benzoquinone fluoroalkylated derivatives
    Cherkasov, V. K.
    Druzhkov, N. O.
    Zolotukhin, A. A.
    Shavyrin, A. S.
    Egorova, E. N.
    RUSSIAN CHEMICAL BULLETIN, 2015, 64 (11) : 2718 - 2724
  • [50] Continuous In Situ Electrogeneration of o-Benzoquinone in Microreactor: Application to High Yield Reaction with Benzenethiols
    Kashiwagi, Tsuneo
    Amemiya, Fumihiro
    Fuchigami, Toshio
    Atobe, Mahito
    JOURNAL OF FLOW CHEMISTRY, 2013, 3 (01) : 17 - 22
12345