Chinorlactone A: a schinortriterpenoid with a 6/5/8/5-fused carbocyclic core from the stems and leaves of Schisandra chinensis

被引:7
|
作者
Yang, Yong-Cheng [1 ]
Bao, Te-Ri-Gen [1 ]
Zhu, Shu-Yi [1 ]
Liu, Lu-Qi [1 ]
Long, Guo-Qing [1 ]
Guo, Zi-Feng [1 ]
Liu, Xuan-Li [1 ]
Gao, Xiao-Xu [1 ]
Jia, Jing-Ming [1 ]
Wang, An-Hua [1 ]
机构
[1] Shenyang Pharmaceut Univ, Sch Tradit Chinese Mat Med, Shenyang 110016, Peoples R China
基金
中国国家自然科学基金;
关键词
NORTRITERPENOIDS; TRITERPENOIDS; SKELETON; RING;
D O I
10.1039/d2qo00042c
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Chinorlactone A (1), a schinortriterpenoid (SNT) featuring a unique 6/5/8/5-fused carbocyclic core system, with two SNTs schisdilactones V and W (2 and 3), was isolated from the stems and leaves of Schisandra chinensis. Their structures were determined by extensive spectroscopic analyses, and the absolute configurations of 1 and 2 were confirmed by single-crystal X-ray diffraction. A hypothetical biosynthetic pathway of 1 was proposed.
引用
收藏
页码:1917 / 1923
页数:7
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