Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes with N-bromosuccinimide as a powerful oxidant

被引：39

作者：

Xu, Daqian ^{[1
,2
]}

Wang, Shoufeng ^{[1
]}

Shen, Zhiqiang ^{[1
]}

Xia, Chungu ^{[1
]}

Sun, Wei ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 14期

基金：

中国国家自然科学基金;

关键词：

NONENZYMATIC KINETIC RESOLUTION; ALPHA-HYDROXY ESTERS; MOLECULAR-OXYGEN; ASYMMETRIC CATALYSIS; AEROBIC OXIDATION; SALEN COMPLEXES; HYDROGENATION; MECHANISM; WATER; KETONES;

D O I：

10.1039/c2ob07087a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We demonstrate an efficient enantioselective oxidation of secondary alcohols catalyzed by Mn(III)-salen complex using N-bromosuccinimide (NBS) as the oxidant. The new protocol is very efficient for the oxidative kinetic resolution of a variety of secondary alcohols, including ortho-substituted benzylic alcohols.

引用

页码：2730 / 2732

页数：3

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