Synthesis, structure characterization and biological activity of layered vanadium oxides [NH3 (CH2)2 NH (CH2)2 NH3][V6O14]

被引：0

作者：

Fu, PP

Wang, XL

Wang, EB ^{[1
]}

Qin, C

Xu, L

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China

[2] Jilin Univ, China Japan Union Hosp, Changchun 130024, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2005年 / 21卷 / 05期

关键词：

polyoxometalate; vanadium oxide; crystal structure; anti-tumor activity;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new layered vanadium oxide [NH3(CH2)(2)NH(CH2)(2)NH3] [V6O14] (compound 1) was synthesized and characterized by elemental analysis, IR spectrometry and single crystal X ray diffraction. The compound crystallizes in a monoclinic space group P2 (1)/n with a 1.0254 ( 2) nm, b = 0.6739 ( 2) nm, c = 1.2400 ( 2) nm, beta = 93.88 (3)degrees, V = 0.8549 (3) nm(3), Z = 2, R-1 = 0.0366, wR(2) = 0.1038. Compound 1 consists of two-dimensional mixed-valence vanadium oxide layers parallelling to the bc plane. The anti-tumor activity of the compound was estimated in three human tumor cell lines in vitro.

引用

页码：509 / 511

页数：3

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