Synthesis of DME from CO2/H2 gas mixture

被引：110

作者：

Naika, Sajo P. ^{[1
]}

Ryu, Taegong ^{[2
]}

Bui, Vy ^{[2
]}

Miller, Jan D. ^{[2
]}

Drinnan, Nicholas B. ^{[3
]}

Zmierczak, Wlodzimierz ^{[2
]}

机构：

[1] Western Res Inst, Laramie, WY 82072 USA

[2] Univ Utah, Coll Mines & Earth Sci, Dept Met Engn, Salt Lake City, UT 84112 USA

[3] Ambre Energy, Brisbane, Qld 4000, Australia

来源：

CHEMICAL ENGINEERING JOURNAL | 2011年 / 167卷 / 01期

关键词：

Dimethyl ether; Carbon dioxide; Methanol synthesis catalyst; Hydrotalcite; DME synthesis catalyst; HZSM-5; gamma-Al2O3; Slurry reactor; Fixed-bed reactor; DIMETHYL-ETHER SYNTHESIS; METHANOL SYNTHESIS; CO2; HYDROGENATION; CARBON-DIOXIDE; CATALYST;

D O I：

10.1016/j.cej.2010.12.087

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The activity and durability of two hybrid bifunctional dimethyl ether (DME) synthesis catalysts: 6CuO-3ZnO-Al2O3/gamma-Al2O3 and 6CuO-3ZnO-1Al(2)O(3)/HZSM-5, have been evaluated for the conversion of CO2/H-2 to DME at 260 degrees C, 5 MPa, and gas per hourly space velocity (GHSV) of 3000 mLg(cat)(-1) h(-1) in fixed-bed and slurry reactors. The catalyst 6CuO-3ZnO-Al2O3/gamma-Al2O3 mostly promoted reverse-water-gas-shift (RWGS) reaction with very low selectivity to DME, and a low conversion of CO2. The other catalyst, 6CuO-3ZnO-1Al(2)O(3)/HZSM-5, showed much higher conversion of CO2 with higher selectivity to DME in both, fixed-bed and slurry reactors. (c) 2011 Elsevier B.V. All rights reserved.

引用

页码：362 / 368

页数：7

共 50 条

[31] Prereduction of Nchwaning Ore in CO/CO2/H2 Gas Mixtures
Schanche, Trygve Lindahl
Tangstad, Merete
MINERALS, 2021, 11 (10)
[32] Computational fluid dynamics modeling and analysis of Pd-based membrane module for CO2 capture from H2/CO2 binary gas mixture
Shin, Dong-Yoon
Hwang, Kyung-Ran
Park, Jong-Soo
Park, Myung-June
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2015, 32 (07) : 1414 - 1421
[33] Computational fluid dynamics modeling and analysis of Pd-based membrane module for CO2 capture from H2/CO2 binary gas mixture
Dong-Yoon Shin
Kyung-Ran Hwang
Jong-Soo Park
Myung-June Park
Korean Journal of Chemical Engineering, 2015, 32 : 1414 - 1421
[34] Benefits from H2 and CO2 additions in argon gas mixtures in GMAW
Schafranski, Lincon Luiz
da Cunha, Tiago Vieira
Nino Bohorquez, Carlos Enrique
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2017, 249 : 158 - 166
[35] Production of synthesis gas (H2 and CO) by high-temperature Co-electrolysis of H2O and CO2
Alenazey, Feraih
Alyousef, Yousef
Almisned, Omar
Almutairi, Ghzzai
Ghouse, Mohammad
Montinaro, Dario
Ghigliazza, Francesco
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (32) : 10274 - 10280
[36] Effect of CO2 and H2 gas mixture in cold water immersion on recovery after eccentric loading
Yoshimura, Miho
Nakamura, Masatoshi
Kasahara, Kazuki
Yoshida, Riku
Murakami, Yuta
Hojo, Tatsuya
Inoue, Goichi
Makihira, Naohisa
Fukuoka, Yoshiyuki
HELIYON, 2023, 9 (10)
[37] CO2 Capture from a Binary CO2/N2 and a Ternary CO2/N2/H2 Mixture by PSA: Experiments and Predictions
Marx, Dorian
Joss, Lisa
Hefti, Max
Gazzani, Matteo
Mazzotti, Marco
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2015, 54 (22) : 6035 - 6045
[38] Experimental implementation of a catalytic membrane reactor for the direct synthesis of DME from H2+CO/CO2
Rodriguez-Vega, Pablo
Ateka, Ainara
Kumakiri, Izumi
Vicente, Hector
Erena, Javier
Aguayo, Andres T.
Bilbao, Javier
CHEMICAL ENGINEERING SCIENCE, 2021, 234
[39] Effects of synthetic gas constituents on combustion and emission behavior of premixed H2/CO/CO2/CNG mixture flames
Yilmaz, Harun
Yilmaz, Ilker
JOURNAL OF THE ENERGY INSTITUTE, 2019, 92 (04) : 1091 - 1106
[40] New Supercritical Method to Capture CO2 from N2 and H2 Gas Mixture in Ammonia/Urea Production Plants
El-Maghraby, Rehab M.
Ramzy, Mahmoud
Aboul-Gheit, Ahmed K.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2023, 63 (01) : 436 - 444

← 1 2 3 4 5 →