Synthesis and characterization of a novel latent ring-opening metathesis polymerization catalyst

被引：2
|
作者：
Sherstobitov, Ivan A. [1 ]
Kiselev, Stanislav A. [1 ]
Lyapkov, Alex A. [1 ]
Yusubov, Mekhman S. [1 ]
Zhdankin, Viktor V. [1 ,2 ]
Yu, Bao-Yi [3 ]
Verpoort, Francis [1 ,4 ]
机构：
[1] Natl Res Tomsk Polytech Univ, Tomsk 634050, Russia
[2] Univ Minnesota, Dept Chem & Biochem, Duluth, MN 55812 USA
[3] Beijing Univ Agr, Coll Biol Sci Engn, Key Lab Urban Agr North China, Minist Agr, Beijing 102206, Peoples R China
[4] Wuhan Univ Technol, Lab Organometall Catalysis & Ordered Mat, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
来源：
TETRAHEDRON LETTERS | 2021年 / 84卷
关键词：
Ruthenium catalyst; Olefin metathesis-controlled initiation; 2; 5-disubstituted; 1; 3; 4-oxadiazoles; Ring-opening metathesis polymerization; Latent catalysts; OLEFIN; COMPLEXES; ROMP;
D O I：
10.1016/j.tetlet.2021.153451
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis and characterization of a novel latent ruthenium catalyst bearing a chelate ligand containing an oxadiazole fragment for the olefin metathesis are described. The main advantages of the utilization of this ligand are the straightforwardness of preparation, mild reaction conditions, and availability of the feedstock. Preliminary study of the catalytic activity of the Ru complex for metathesis reactions demonstrated its inactive nature for the ring-closing metathesis (RCM), but an excellent thermo-switchability for the ring-opening metathesis polymerization of norbornene. (c) 2021 Elsevier Ltd. All rights reserved.
引用
收藏
页数：4
相关论文
共 50 条
  • [31] Novel amphiphilic architectures by ring-opening metathesis polymerization of macromonomers
    Heroguez, V
    Gnanou, Y
    Fontanille, M
    MACROMOLECULES, 1997, 30 (17) : 4791 - 4798
  • [32] Novel amphiphilic architectures by ring-opening metathesis polymerization of macromonomers
    Gnanou, Y
    Heroguez, V
    Fontanille, M
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 29 - POLY
  • [33] Polymers with novel topologies by ring-opening metathesis polymerization of macromonomers
    Grande, D
    Six, JL
    Breunig, S
    Heroguez, V
    Fontanille, M
    Gnanou, Y
    POLYMERS FOR ADVANCED TECHNOLOGIES, 1998, 9 (10-11) : 601 - 612
  • [34] Fullerene containing norbornenes: synthesis and ring-opening metathesis polymerization
    Miftakhov, Mansur S.
    Mikheev, Vladimir V.
    Torosyan, Seda A.
    Biglova, Yuliya N.
    Gimalova, Fanuza A.
    Menshov, Vladimir M.
    Mustafin, Akhat G.
    TETRAHEDRON, 2014, 70 (43) : 8040 - 8046
  • [35] Synthesis of dendronized polymers via ring-opening metathesis polymerization
    Jung, Hwayoon
    Week, Marcus
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [36] The synthesis and ring-opening metathesis polymerization of peptide functionalized norbornenes
    Biagini, SCG
    Davies, RG
    Gibson, VC
    Giles, MR
    Marshall, EL
    North, M
    Robson, DA
    CHEMICAL COMMUNICATIONS, 1999, (03) : 235 - 236
  • [37] Synthesis of Functionalizable and Degradable Polymers by Ring-Opening Metathesis Polymerization
    Fishman, Joshua M.
    Kiessling, Laura L.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (19) : 5061 - 5064
  • [38] Synthesis of lactose polymers for the galectins by ring-opening metathesis polymerization
    Pohl, NL
    Leffler, H
    Kiessling, LL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 20 - ORGN
  • [39] Synthesis of Stereoregular Polymers through Ring-Opening Metathesis Polymerization
    Schrock, Richard R.
    ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (08) : 2457 - 2466
  • [40] Schrock Catalyst Triggered, Ring-Opening Metathesis Polymerization Based Synthesis of Functional Monolithic Materials
    Scheibitz, Bettina
    Prager, Andrea
    Buchmeiser, Michael R.
    MACROMOLECULES, 2009, 42 (10) : 3493 - 3499
12345