Optical response of thiosalicylic-capped CdS nanocrystals to terbium ions

被引:7
|
作者
Tiseanu, C
Mehra, R
Kho, R
机构
[1] Natl Inst Laser Plasma & Radiat Phys, RO-76900 Bucharest, Romania
[2] Univ Calif Riverside, Dept Neurosci, Environm Toxicol Grad Program, Riverside, CA 92521 USA
关键词
CdS nanocrystals; thiosalicylic acid; terbium ions; absorption; photoluminescence;
D O I
10.1016/j.jphotochem.2005.01.017
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of terbium ion addition on the optical spectra of CdS nanocrystals capped with thiosalicylic acid were investigated by means of absorption and steady-state photoluminescence spectroscopy. Upon terbium addition, the CdS absorption was modified around the first exciton peak while the CdS photoluminescence experienced selective enhancing and quenching processes. The results indicated that, most probably, the two types of changes are decoupled. The interpretation considered the key role played by the capping ligand in the optical response of nanocrystals to the lanthanide ions. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:169 / 173
页数:5
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