Synthesis of ZSM-5/porous mullite honeycomb composite from sintered Malaysia kaolin via hydrothermal processing

被引：1
|
作者：
Katsuki, H
Kamochi, N
Komarneni, S
机构：
[1] Saga Ceram Res Lab, Saga 8440024, Japan
[2] Penn State Univ, Dept Agron, University Pk, PA 16802 USA
[3] Penn State Univ, Mat Res Lab, University Pk, PA 16802 USA
来源：
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN | 2001年 / 109卷 / 01期
关键词：
kaolin; ZSM-5; zeolite; silica-glass; mullite; hydrothermal treatment;
D O I：
10.2109/jcersj.109.33
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The synthesis and properties of ZSM-5 film on a porous mullite honeycomb have been investigated using Malaysia kaolin. Amorphous silica-glass in the kaolin honeycomb sintered at 1450 degreesC was used as a source for ZSM-5 formation. The honeycomb was hydrothermally treated in NaOH, tetrapropylammonium bromide, and water to prepare a novel ZSM-5/mullite honeycomb composite via in-situ crystallization at 160 to 180 degreesC. This paper describes the formation of mullite from Malaysia kaolin at 1400 to 1500 degreesC, the effects of hydrothermal conditions such as reaction temperature, time, and concentration of NaOH solution on the formation of ZSM-5 crystals on the honeycomb, and on the porous properties of the composite.
引用
收藏
页码：33 / 38
页数：6
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