Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C-C bond cleavage

被引：11

作者：

Cui, Suya ^{[1
]}

Wu, Xiaoyun ^{[1
]}

Ma, Wei ^{[1
]}

Tang, Weijun ^{[1
]}

Sun, Huaming ^{[1
]}

Xiao, Jianliang ^{[2
]}

Xue, Dong ^{[1
]}

Wang, Chao ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710119, Peoples R China

[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, England

来源：

GREEN SYNTHESIS AND CATALYSIS | 2021年 / 2卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Iron catalysis; Dehydrogenation; Coupling; C -C bond cleavage; N; -heterocycle; ASYMMETRIC HYDROGENATION; ALCOHOLS; IMINES; REARRANGEMENT; TITANOCENE; ACCESS;

D O I：

10.1016/j.gresc.2021.04.007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron catalyzed coupling of fl-amino alcohols with allylic alcohols for the synthesis of 3,4-dihydro-2H-pyrrole derivatives has been developed. Mechanistic studies suggest that the reaction involves iron catalyzed dehydro-genative coupling and C-C bond cleavage processes.

引用

页码：307 / 310

页数：4

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