Anion dependant self-assembly and the first X-ray structure of a neutral homoleptic lanthanide salen complex Tb4(salen)6

被引：59

作者：

Yang, Xiaoping ^{[1
]}

Jones, Richard A. ^{[1
]}

Wong, Wai-Kwok ^{[2
]}

机构：

[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA

[2] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 28期

关键词：

D O I：

10.1039/b803901a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of H(2)salen (H(2)L)with Tb(OAc)(3)center dot 4H(2)O (3 : 2) in MeOH-MeCN under reflux gave homoleptic Tb(4)L(6) (1) in 40% yield; in contrast, similar reactions of Tb(NO(3))(3)center dot 6H(2)O and LnCl(3)center dot 6H(2)O (Ln = Tb, Nd and Yb) gave [TbL(NO(3))(MeOH)](2)(mu-H(2)L) (2) and [LnL(Cl)(MeOH)](2)(mu-H(2)L) (Ln = Tb (3), Nd (4) and Yb (5); H(2)L = N, N'-ethylenebis(salicylideneimine)).

引用

页码：3266 / 3268

页数：3

共 37 条

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