Anionic polymerization of phenyl glycidyl ether

被引：9
|
作者：
Tanzer, W
Buttner, K
Ludwig, I
机构：
[1] Martin-Luther-Univ. Halle-Wittenberg, Fb. Chem./Inst. Tech. M., D-06217 Merseburg, Geusaer Strasse
来源：
POLYMER | 1996年 / 37卷 / 06期
关键词：
phenyl glycidyl ether; anionic polymerization; oligo(hydroxy ethers);
D O I：
10.1016/0032-3861(96)87283-1
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
In the anionic polymerization of phenyl glycidyl ether (PGE) initiated by sodium caprolactam (NaCL) or sodium caprolactam/N-acetyl caprolactam (NaCL/AcCL), oligo(hydroxy ethers) with different structures and distributions are formed depending on the temperature and concentration of the initiating system. The progress of the reaction was followed by using epoxide titration and high-performance liquid chromatography. The properties of the reaction products were determined by means of vapour-phase osmometry. The melting ranges of the isolated products were found to be from 72 to 120 degrees C and molar masses from 340 to 4000 g mol(-1).
引用
收藏
页码：997 / 1003
页数：7
相关论文
共 50 条
  • [41] Polymerization of glycidyl phenyl ether with phosphonic acid esters as novel thermally latent initiators
    Kim, M
    Sanda, F
    Endo, T
    MACROMOLECULES, 1999, 32 (25) : 8291 - 8295
  • [42] Stereoregular polymerization of glycidyl phenyl ether catalyzed by dibutyltin oxide tributyl phosphate condensates
    Xu, JJ
    Hou, KY
    Song, R
    Li, LP
    Yu, YZ
    POLYMER BULLETIN, 1998, 40 (4-5) : 395 - 400
  • [43] POLYMERIZATION OF CHLOROPHENYL GLYCIDYL ETHERS .8. INITIATION OF THE POLYMERIZATION OF PARA-CHLOROPHENYL GLYCIDYL ETHER AND PHENYL GLYCIDYL ETHER BY THE SYSTEM ALUMINUM ISOPROPOXIDE AND ZINC-CHLORIDE (1-1)
    JEDLINSKI, Z
    BERO, M
    SZEWCZYK, P
    DWORAK, A
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1981, 19 (03) : 749 - 757
  • [44] SELECTIVE POLYMERIZATION OF GLYCIDYL VINYL ETHER
    SASANO, M
    NISHIKUBO, T
    KOBUNSHI RONBUNSHU, 1990, 47 (07) : 597 - 604
  • [45] Liquid Crystal Poly(glycidyl ether)s by Anionic Polymerization and Polymer-Analogous Reaction
    Maria Chiara Bignozzi
    Sante A Angeloni
    Michele Laus
    Luca Incicco
    Oriano Francescangeli
    Dietmar Wolff
    Giancarlo Galli
    Emo Chiellini
    Polymer Journal, 1999, 31 : 913 - 919
  • [46] Novel thermosensitive polyethers prepared by anionic ring-opening polymerization of glycidyl ether derivatives
    Aoki, S
    Koide, A
    Imabayashi, S
    Watanabe, M
    CHEMISTRY LETTERS, 2002, (11) : 1128 - 1129
  • [47] Liquid crystal poly(glycidyl ether)s by anionic polymerization and polymer-analogous reaction
    Bignozzi, Maria Chiara
    Angeloni, Sante A.
    Laus, Michele
    Incicco, Luca
    Francescangeli, Oriano
    Wolff, Dietmar
    Galli, Giancarlo
    Chiellini, Emo
    Polymer Journal, 1999, 31 (11 pt 1): : 913 - 919
  • [48] Liquid crystal poly(glycidyl ether)s by anionic polymerization and polymer-analogous reaction
    Bignozzi, MC
    Angeloni, SA
    Laus, M
    Incicco, L
    Francescangeli, O
    Wolff, D
    Galli, G
    Chiellini, E
    POLYMER JOURNAL, 1999, 31 (11) : 913 - 919
  • [49] Reaction of phenyl glycidyl ether with some heterocycles
    E. G. Mesropyan
    G. B. Ambartsumyan
    A. A. Avetisyan
    A. S. Galstyan
    Chemistry of Heterocyclic Compounds, 2008, 44 : 650 - 653
  • [50] REACTION OF PHENYL GLYCIDYL ETHER WITH TRIPHENYL ISOCYANURATE
    KORSHAK, VV
    KOMAROVA, LI
    VINOGRADOVA, SV
    SALAZKIN, SN
    BULGAKOVA, IA
    ZABOROVSKAYA, EE
    NIKOLAICHIK, VP
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1981, 30 (07): : 1335 - 1336
12345