Effect of organic additives in electrolyte solutions on behavior of lithium metal anode

被引:19
|
作者
Matsuda, Y [1 ]
Takemitsu, T [1 ]
Tanigawa, T [1 ]
Fukushima, T [1 ]
机构
[1] Kansai Univ, Dept Appl Chem, Fac Engn & High Technol Res Ctr, Suita, Osaka 5648680, Japan
关键词
polyvinylpyrrolidone; lithium metal batteries; dendrite;
D O I
10.1016/S0378-7753(01)00698-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Addition effect of polymer materials, polyvinylpyrrolidone (PVP), polyacrylonitrile (PAN) and polyethylene oxide (PEO) in the electrolyte solutions, ethylene carbonate (EC)-propylene carbonate (PC) (1:1 vol.)/ 0.25 mol/l LiBF4 or Li (CF3SO2)(2)N, was investigated. In the electrolyte solutions containing PVP the charge-discharge current efficiency of lithium on Ni electrode was the highest and the interface resistance between a lithium metal electrode and the electrolyte solution was small during charge-discharge cycle. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:589 / 591
页数:3
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