High-throughput evaluation of in situ-generated cobalt(III) catalysts for acyl fluoride synthesis

被引：19

作者：

Lee, Graham M.

Clement, Roxanne

Baker, R. Tom ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem & Biomol Sci, 30 Marie Curie, Ottawa, ON K1N 6N5, Canada

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2017年 / 7卷 / 21期

基金：

加拿大自然科学与工程研究理事会;

关键词：

NUCLEOPHILIC FLUORINATION; COMPLEXES; LIGANDS;

D O I：

10.1039/c7cy01519d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using a high-throughput experimental procedure, a series of cobalt(III) complexes of the general formula (CpCo)-Co-R(I)(X)(L) were prepared and screened for their activity towards the catalytic nucleophilic fluorination of benzoyl chloride. A highly active catalyst was identified, and successfully employed in a mild and effective protocol for the synthesis of a group of acyl fluoride compounds.

引用

页码：4996 / 5003

页数：8

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