Small quartz silica spheres induced disorder in octylcyanobiphenyl (8CB) liquid crystals: A thermal study

A photopyroelectric technique has been applied to the study of specific heat and thermal conductivity of homeotropically aligned mixtures of small quartz spheres (aerosil) and octylcyanobiphenyl (8CB) with concentration 0 less than or equal to rho (s) less than or equal to 0.04 g/cm(3). Thermal conductivity data show that, even at these very low concentrations, an annealing of the disorder introduced by the aerosil takes place on cooling at the smectic-A-nematic (Sm-A-N) phase transition and not only at the nematic-isotropic (N-I) one. This means that there is some elastic strain in the nematic phase of the sample which is not quenched. Accordingly the suppression of the N-I transition temperature as a function of rho (s) does not fit a random field with a random dilution model that accounts for random quenched disorder only. High resolution specific heat measurements at the A-N and N-I transition show the effect of the aerosil is not the same. While in the first case its peak is suppressed with increasing concentration, in the second case there are some indications that outside the two-phase coexistence region it is enhanced. The effect of surface-induced alignment is also discussed to explain some discrepancies between our data and the ones reported in literature. It is concluded that the amount of disorder in the sample does not depend on rho (s) only, but also on other variables such as external fields. Finally, a relaxation phenomenon in the aerosil network that partially compensate the disordering effect of the particles is suggested to explain the concentration dependence of the transition temperatures.