Plasma Modification of Catalysts for Cathode Reduction of Hydrogen Peroxide in Fuel Cells

被引：10

作者：

Brueser, Volker ^{[1
]}

Savastenko, Natalie ^{[1
]}

Schmuhl, Andreas ^{[2
]}

Junge, Henrik ^{[3
]}

Herrmann, Iris ^{[4
]}

Bogdanoff, Peter ^{[4
]}

Schroeder, Karsten ^{[1
]}

机构：

[1] Inst Low Temp Plasma Phys, D-17489 Greifswald, Germany

[2] AMT Analysenmesstech GmbH, D-18059 Rostock, Germany

[3] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

[4] Hahn Meitner Inst Berlin GmbH, D-14109 Berlin, Germany

来源：

PLASMA PROCESSES AND POLYMERS | 2007年 / 4卷

关键词：

catalysts; fuel cells; plasma treatment; pyrolysis; surface modification; X-ray photoelectron spectroscopy (XPS);

D O I：

10.1002/ppap.200730409

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Plasma techniques have been extensively utilized in catalysis. Catalyst preparation using plasma treatment allows to improve dispersion, enhancing the catalyst performance and stability. In this paper, the low-pressure radio frequency (RF) discharge is shown as an efficient method to enhance the activity of cobalt tetramethoxyphenylporphyrin (CoTMPP)-based electrocatalyst for the reduction of hydrogen peroxide. It was found that a carbon-supported CoTMPP catalyst (20% CoTMPP/C) treated by plasma presents two-fold higher catalytic activity than catalyst prepared without plasma treatment. The influence of catalyst treatment on elemental surface and bulk concentration and performance of catalysts for hydrogen peroxide in a fuel cell was investigated.

引用

页码：S94 / S98

页数：5

共 50 条

[21] Nanostructured palladium-silver coated nickel foam cathode for magnesium-hydrogen peroxide fuel cells
Yang, Weiqian
Yang, Shaohua
Sun, Wei
Sun, Gongquan
Xin, Qin
[J]. ELECTROCHIMICA ACTA, 2006, 52 (01) : 9 - 14
[22] Cathode electrocatalyst selection and deposition for a direct borohydride/hydrogen peroxide fuel cell
Gu, Lifeng
Luo, Nie
Miley, George H.
[J]. JOURNAL OF POWER SOURCES, 2007, 173 (01) : 77 - 85
[23] A membraneless hydrogen peroxide fuel cell using Prussian Blue as cathode material
Shaegh, Seyed Ali Mousavi
Nam-Trung Nguyen
Ehteshami, Seyyed Mohsen Mousavi
Chan, Siew Hwa
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (08) : 8225 - 8228
[24] A direct methanol-hydrogen peroxide fuel cell with a Prussian Blue cathode
Yan, X. H.
Zhao, T. S.
An, L.
Zhao, G.
Shi, L.
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (09) : 5135 - 5140
[25] In situ detection of hydrogen peroxide in PEM fuel cells
Liu, W
Zuckerbrod, D
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (06) : A1165 - A1170
[26] A study of cathode catalysis for the aluminium hydrogen peroxide semi-fuel cell
Bessette, RR
Cichon, JM
Dischert, DW
Dow, EG
[J]. JOURNAL OF POWER SOURCES, 1999, 80 (1-2) : 248 - 253
[27] PtSnP/C and PtSn/C as efficient cathode catalysts for oxygen reduction reaction in microbial fuel cells
Li, Baitao
He, Zhenzhen
Wang, Mian
Wang, Xiujun
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (08) : 5261 - 5271
[28] Oxygen Reduction on Pt(111) Cathode of Fuel Cells
Son, Do Ngoc
Nakanishi, Hiroshi
David, Melanie Yadao
Kasai, Hideaki
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2009, 78 (11)
[29] Electrochemical and structural analysis of cathode catalysts and electrodes for fuel cells
Kenis, Paul J. A.
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
[30] Platinum-free air cathode catalysts for fuel cells
Sawai, Keijiro
Uda, Daisaku
Shirai, Keiichi
[J]. ELECTROCHEMISTRY, 2007, 75 (02) : 163 - 165

← 1 2 3 4 5 →