Structural study of terpyridine and o-phenanthroline complexes of iridium(III)

被引：8
|
作者：
Burger, K
Wagner, FE
Vértes, A
Bencze, É
Mink, J
Labádi, I
Nemes-Vetéssy, Z
机构：
[1] Eotvos Lorand Univ, Dept Nucl Chem, H-1518 Budapest, Hungary
[2] Hungarian Acad Sci, Res Grp Biocoordinat Chem, H-6701 Szeged, Hungary
[3] Univ Munich, Dept Tech Phys, D-87547 Garching, Germany
[4] Hungarian Acad Sci, Chem Res Ctr, Inst Isotope & Surface Chem, H-1525 Budapest, Hungary
[5] Univ Veszprem, Dept Analyt Chem, H-8501 Veszprem, Hungary
[6] Attila Jozsef Univ, Dept Inorgan & Analyt Chem, H-6701 Szeged, Hungary
来源：
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2001年 / 62卷 / 11期
基金：
美国国家科学基金会;
关键词：
Mossbauer spectroscopy;
D O I：
10.1016/S0022-3697(01)00075-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Combined Mossbauer and vibrational spectroscopic investigations revealed the presence of three structural units in the bis-terpyridine-iridium(III) complex in the solid state. A similar investigation of mixed o-phenanthroline halide complexes of iridium(HI) indicated that the procedures elaborated to synthesize the cis and trans isomers of these complexes in fact led to the same product, the cisisomer. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2059 / 2068
页数：10
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