High-pressure solubilities of hydrogen, nitrogen, and carbon monoxide iu dodecane from 344 to 410 K at pressures to 13.2 MPa

被引:60
|
作者
Gao, W [1 ]
Robinson, RL [1 ]
Gasem, KAM [1 ]
机构
[1] Oklahoma State Univ, Sch Chem Engn, Stillwater, OK 74078 USA
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D O I
10.1021/je9801664
中图分类号
O414.1 [热力学];
学科分类号
摘要
The solubilities of hydrogen, nitrogen, and carbon monoxide in dodecane were measured using a static equilibrium cell over the temperature range from 344.3 to 410.9 K at pressures to 13.24 MPa. The uncertainty in these measurements is estimated to be less than 0.001 in mole fraction. The data are represented with root-mean-square errors of less than 0.003 mole fraction by the Soave-Redlich-Kwong and Peng-Robinson equations of state when a single empirical interaction parameter, C-ij, is used for each binary system.
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页码:130 / 132
页数:3
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