Unexpected photolytic decomposition of alkyl azides under mild conditions

被引：0
|
作者：
Abbenante, Giovanni [1 ]
Le, Giang T. [1 ]
Fairlie, David P. [1 ]
机构：
[1] Univ Queensland, Inst Mol Biosci, Ctr Drug Design & Dev, Brisbane, Qld, Australia
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 43期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alkyl azides have been found to undergo an unexpectedly facile photodecomposition under mild conditions (laboratory light) and the reaction gives rise to small amounts of aldehydes and monoacyl aminal rearrangement products that can dramatically impact on the uses of azides in chemistry, biology and medicine.
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收藏
页码：4501 / 4503
页数：3
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