Unexpected photolytic decomposition of alkyl azides under mild conditions

被引：0

作者：

Abbenante, Giovanni ^{[1
]}

Le, Giang T. ^{[1
]}

Fairlie, David P. ^{[1
]}

机构：

[1] Univ Queensland, Inst Mol Biosci, Ctr Drug Design & Dev, Brisbane, Qld, Australia

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 43期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkyl azides have been found to undergo an unexpectedly facile photodecomposition under mild conditions (laboratory light) and the reaction gives rise to small amounts of aldehydes and monoacyl aminal rearrangement products that can dramatically impact on the uses of azides in chemistry, biology and medicine.

引用

页码：4501 / 4503

页数：3

共 50 条

[1] A Simple and Convenient Synthesis of Alkyl Azides under Mild Conditions
1600,
[2] A SIMPLE AND CONVENIENT SYNTHESIS OF ALKYL AZIDES UNDER MILD CONDITIONS
ITO, M
KOYAKUMARU, K
OHTA, T
TAKAYA, H
SYNTHESIS-STUTTGART, 1995, (04): : 376 - 378
[3] UNEXPECTED DECOMPOSITION OF TRIPHENYL(METHYL)STIBONIUM BROMIDE UNDER MILD CONDITIONS
PARRIS, GE
LONG, GG
ANDREWS, BC
PARRIS, RM
JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (07): : 1276 - 1277
[4] THERMAL AND PHOTOLYTIC DECOMPOSITION OF LEAD AZIDES IN AIR
TODD, G
PARRY, E
NATURE, 1962, 196 (4851) : 250 - &
[5] A Ru-catalyzed one-pot synthesis of homopropargylic amines from alkyl azides under photolytic conditions
Jeong, Wook
Lee, Ji Hyung
Kim, Jungjoon
Lee, Won Jong
Seong, Ju-Hwa
Park, Jaiwook
Rhee, Young Ho
RSC ADVANCES, 2014, 4 (40): : 20632 - 20635
[6] PHOTOCHEMICAL DECOMPOSITION OF ALKYL AZIDES
MORIARTY, RM
RAHMAN, M
TETRAHEDRON, 1965, 21 (10) : 2877 - &
[7] Copper-Catalyzed Vicinal Oxyazidation and Diazidation of Styrenes under Mild Conditions: Access to Alkyl Azides
Lu, Ming-Zhu
Wang, Cheng-Qiang
Loh, Teck-Peng
ORGANIC LETTERS, 2015, 17 (24) : 6110 - 6113
[8] Controlled decomposition of azides under base mediated conditions
Bahde, Robert J.
Trenkle, William C.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
[9] DIRECT AND PHOTOSENSITIZED DECOMPOSITION OF ALKYL AZIDES
MORIARTY, RM
REARDON, RC
TETRAHEDRON, 1970, 26 (06) : 1379 - &
[10] Copper catalyzed reduction of azides with diboron under mild conditions
Liu, Liwen
Wang, Qianwen
Liu, Yu
Zhang, Xiao
Lu, Da
Deng, Shengqi
Gao, Yihua
Chen, Yang
TETRAHEDRON LETTERS, 2020, 61 (14)

← 1 2 3 4 5 →