14-Hydroxy-11-[(E)-4-methoxybenzylidene]-8-(4-methoxyphenyl)-5-thia-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15(23),16,18,20-pentaen-10-one

被引：2

作者：

Kumar, Raju Suresh ^{[2
]}

Osman, Hasnah ^{[2
]}

Rahim, A. S. Abdul ^{[3
]}

Hemamalini, Madhukar ^{[1
]}

Fun, Hoong-Kun ^{[1
]}

机构：

[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia

[2] Univ Sains Malaysia, Sch Chem Sci, Usm 11800, Penang, Malaysia

[3] Univ Sains Malaysia, Sch Pharmaceut Sci, Usm 11800, Penang, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

D O I：

10.1107/S160053681104061X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C36H32N2O4S, the piperidine ring adopts a chair conformation, while the five-membered pyrrolidine (with a C atom as the flap atom) and thiazolidine (with the S atom as the flap atom) rings adopt envelope conformations. The naphthalene ring system makes dihedral angles of 18.82 (5) and 40.92 (5)degrees with the two methoxy-substituted benzene rings. In the crystal, centrosymmetrically-related molecules are linked into dimers via pairs of C-H center dot center dot center dot O and C-H center dot center dot center dot N hydrogen bonds. An intramolecular O-H center dot center dot center dot N hydrogen bond is also observed. The crystal structure is further stabilized by C-H center dot center dot center dot pi interactions.

引用

页码：O2881 / +

页数：15

共 5 条

[1] 11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15,17,19(23),20-pentaen-10-one
Kumar, Raju Suresh
Osman, Hasnah
Rahim, Aisyah Saad Abdul
Hemamalini, Madhukar
Fun, Hoong-Kun
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O3045 - U2019
[2] 11-[(E)-4-Bromobenzylidene]-8-(4-bromophenyl)-14-hydroxy-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22), 15,17,19(23),20-pentaen-10-one
Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Hemamalini, Madhukar
Fun, Hoong-Kun
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2926 - U1167
[3] 11-[(E)-2-Fluorobenzylidene[-8-(2-fluorophenyI)-14-hydroxy-6-thia-3,13-diazaheptacyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7)._0(19,23)[tetracosa-1(22),15(23),16,18,20-pentaen-10-one
Kumar, Raju Suresh
Osman, Hasnah
Almansour, Abdulrahman I.
Arshad, Suhana
Razak, Ibrahim Abdul
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2094 - +
[4] 11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-6-thia-3,13-diazahepta-cyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]-tetracosa-1(22),15(23),16,18,20-pentaen-10-one
Kumar, Raju Suresh
Osman, Hasnah
Almansour, Abdulrahman I.
Arshad, Suhana
Razak, Ibrahim Abdul
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2013 - +
[5] Crystal structure of 8-(2-methylphenyl)-11-[(E)-(2-methylphenyl)-methylidene]-14-hydroxy-3,13-diazaheptacyclo-[13.7.1.9,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15,17,19(23),20-pentaen-10-one methanol monosolvate, C37H34N2O2•CH3OH, C38H38N2O3
Almansour, Abdulrahman Ibrahim
Kumar, Raju Suresh
Arumugam, Natarajan
Nagalakshmi, Ramachandran Aruna
Suresh, Janakiraman
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2014, 229 (02): : 175 - 177

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