11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15,17,19(23),20-pentaen-10-one

被引:1
|
作者
Kumar, Raju Suresh [2 ]
Osman, Hasnah [2 ]
Rahim, Aisyah Saad Abdul [3 ]
Hemamalini, Madhukar [1 ]
Fun, Hoong-Kun [1 ]
机构
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
[2] Univ Sains Malaysia, Sch Chem Sci, Usm 11800, Penang, Malaysia
[3] Univ Sains Malaysia, Sch Pharmaceut Sci, Usm 11800, Penang, Malaysia
关键词
D O I
10.1107/S1600536810043874
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C35H30N2O2, the piperidine ring adopts a chair conformation and the pyrrolidine ring adopts an envelope conformation. The naphthalene ring makes dihedral angles of 24.56 (3) and 36.13 (4)degrees with the terminal phenyl rings. The dihedral angle between the two terminal phenyl rings is 55.27 (5)degrees. One of the C atoms in the pyrrolidine ring is disordered over two sites, with a refined occupany ratio of 0.670 (3):0.330 (3). An intramolecular O-H center dot center dot center dot N hydrogen bond generates an S(6) ring. In the crystal structure, inversion dimers linked by pairs of C-H center dot center dot center dot O hydrogen bonds generate R-2(2)(18) loops within sheets of molecules lying parallel to the bc plane.
引用
收藏
页码:O3045 / U2019
页数:14
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