UV-Light-Irradiated Trifluoromethylation of Diheteroaryl Disulfides with CF3SO2Na

被引：6

作者：

Cao, Bao-Qian ^{[1
,2
]}

Qiu, Yi-Feng ^{[1
,2
]}

Zhang, Xi ^{[1
,2
]}

Zhu, Zheng-He ^{[1
,2
]}

Quan, Zheng-Jun ^{[1
,2
]}

Wang, Xi-Cun ^{[1
,2
]}

机构：

[1] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China

[2] Gansu Int Sci & Technol Cooperat Base Water Reten, Lanzhou 730070, Gansu, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 2019卷 / 06期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

Trifluoromethylation; Disulfides; Heterocycles; Ketones; Radical reactions; C-H TRIFLUOROMETHYLATION; OXIDATIVE TRIFLUOROMETHYLTHIOLATION; CATALYZED TRIFLUOROMETHYLATION; FLUORINATED ETHERS; BOND FORMATION; ALKENES; CHEMISTRY; DECOMPOSITION; THIOETHERS; ALDEHYDES;

D O I：

10.1002/ejoc.201801565

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple protocol for the UV light irradiated preparation of heteroaryl trifluoromethyl thioethers from disulfides and inexpensive, environmentally sodium triflinate (CF3SO2Na) has been developed. The features of simple and clean reaction conditions, in moderate to good yields, and broad substrate scope render this new approach synthetically attractive for the preparation of potentially pharmaceutically active compounds.

引用

页码：1208 / 1214

页数：7

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