Ethylene vinyl acetate and ethylene vinyl alcohol copolymer for thermal spray coating application

被引：48
|
作者：
Tambe, S. P. [1 ]
Singh, S. K. [1 ]
Patri, M. [1 ]
Kumar, Dhirendra [1 ]
机构：
[1] Naval Mat Res Lab, Ambernath 421506, India
来源：
PROGRESS IN ORGANIC COATINGS | 2008年 / 62卷 / 04期
关键词：
EVA; EVAI; hydrolysis; flame spray; adhesion;
D O I：
10.1016/j.porgcoat.2008.02.006
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Ethylene vinyl acetate (EVA) copolymer with varying vinyl acetate (VAc) content, viz. 18%, 28% and 40% has been hydrolyzed using alcoholic NaOH solution. Fourier Transform Infrared Spectroscopy (FTIR) analyses of hydrolyzed polymer showed the presence of both OH group and acetate group indicating that the EVA has been partially hydrolyzed. Differential Scanning Calorimeter (DSC) and Thermo Gravimetric Analyzer (TGA) of EVA and hydrolyzed EVA showed large difference in melting and decomposition temperature, respectively. Hydrolyzed EVA showed higher tensile strength and elongation at break compared to corresponding EVA. Blends of different grades of EVA and ethylene vinyl alcohol (EVAI) with low density polyethylene (LDPE) were applied on grit blasted mild steel surface by flame spray technique. FTIR analysis of blends before and after coating,showed no degradation during flame spray. Measurement of adhesion strength of these coating showed that adhesion strength increased on hydrolysis of EVA. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：382 / 386
页数：5
相关论文
共 50 条
  • [21] Property of ethylene vinyl acetate copolymer in melting processing
    Chen, Zhe
    Fang, Pengfei
    Wang, Hongmei
    Zhang, Shaoping
    Wang, Shaojie
    JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 101 (03) : 2022 - 2026
  • [22] Impact toughening of polypropylene by ethylene vinyl acetate copolymer
    Gupta, A.K., 1600, (45):
  • [23] ALKALINE SAPONIFICATION OF ETHYLENE-VINYL ACETATE COPOLYMER
    IWASAKI, H
    YONEZU, K
    KOBUNSHI RONBUNSHU, 1978, 35 (01) : 33 - 39
  • [24] STUDY OF DYNAMIC MECHANICAL PROPERTIES OF POLYVINYL CHLORIDE)-ETHYLENE VINYL ACETATE COPOLYMER AND POLYVINYL CHLORIDE)-CHLORINATED ETHYLENE VINYL ACETATE COPOLYMER MIXTURES
    MARCINCIN, K
    POLLAK, V
    ROMANOV, A
    JOURNAL OF APPLIED POLYMER SCIENCE, 1972, 16 (09) : 2239 - +
  • [25] Effects of crystallinity and crosslinking on the thermal and rheological properties of ethylene vinyl acetate copolymer
    Sung, YT
    Kum, CK
    Lee, HS
    Kim, JS
    Yoon, HG
    Kim, WN
    POLYMER, 2005, 46 (25) : 11844 - 11848
  • [26] Thermal Oxidation of Ethylene Copolymer with Vinyl Acetate in the Presence of Petroleum Polymer Resin
    Perelygina R.A.
    Starostina I.A.
    Zagidullin A.I.
    Garipov R.M.
    Rusanova S.N.
    Stoyanov O.V.
    Polymer Science - Series D, 2023, 16 (02) : 340 - 344
  • [27] Investigation of Ethylene/Vinyl Acetate Copolymer (EVA) by thermal analysis DSC and DMA
    Stark, W.
    Jaunich, M.
    POLYMER TESTING, 2011, 30 (02) : 236 - 242
  • [28] Microstructure and thermal properties of ethylene-(vinyl acetate) copolymer/rectorite nanocomposites
    Fang, PF
    Chen, Z
    Zhang, SP
    Wang, SJ
    Wang, LY
    Feng, JW
    POLYMER INTERNATIONAL, 2006, 55 (03) : 312 - 318
  • [29] Irradiation effects on thermal, surface, and physicomechanical properties of ethylene and vinyl acetate copolymer
    Gladkikh Y.Y.
    Shcherbina A.A.
    Chalykh A.E.
    Khasbiullin R.R.
    Stepanenko V.Y.
    Puryaeva T.P.
    Polymer Science Series D, 2011, 4 (1) : 20 - 26
  • [30] Thermal Characterization of Vinyl Acetate—Ethylene Copolymers
    N. Gupta
    R. K. Srivastava
    V. Choudhary
    I. K. Varma
    S. Patnaik
    Journal of Thermal Analysis and Calorimetry, 1999, 58 : 509 - 515
12345