Engineering of non-interpenetrating 3-D and 2-D networks and guest adsorption based on 4,4′-di(3-methyl)pyridyl sulfide copper(II) complexes

被引：24

作者：

Su, XC ^{[1
]}

Zhu, SR ^{[1
]}

Lin, HK ^{[1
]}

Leng, XB ^{[1
]}

Chen, YT ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 21期

关键词：

D O I：

10.1039/b104515f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new coordination compounds, [Cu(L)(2)SO4].0.5H(2)O .0.5CH(2)Cl(2) (1) and [Cu(L)(2)(SCN)(2)]. 3CHCl(3) (2), were synthesized and structurally characterized. The molecular architectures of the 4,4'-di(3-methyl) pyridyl sulfide (L) coordination polymer networks are anion dependent. The molecular architecture of 1 is a 3-D non-interpenetrating network, SO42- serving as a bridging ligand to connect two copper ions resulting in a rhombic box with a volume of 793 Angstrom (3). While 2 is a 2-D planar network with SCN- acting as a mono-coordinating ligand. Guest adsorption experiments show that 1 prefers to selectively adsorb 4-chlorophenol rather than nitrobenzene and benzophenone and DMF. In contrast, 2 does not adsorb any of the above guest species.

引用

页码：3163 / 3168

页数：6

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