Crystal structure of tris(2-hydroxyethyl)ammonium bromide

被引:0
|
作者
Yilmaz, VT [1 ]
Icbudak, H [1 ]
Olmez, H [1 ]
Howie, RA [1 ]
机构
[1] UNIV ABERDEEN,DEPT CHEM,ABERDEEN AB9 2UE,SCOTLAND
来源
TURKISH JOURNAL OF CHEMISTRY | 1996年 / 20卷 / 01期
关键词
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure of tris(2-hydroxyethyl)ammonium bromide, [HN(CH2CH2OH)(3)]BT, was determined as rhombohedral by single crystal X-ray diffractometer. The final R value was found to be 0.032 for 576 observed reflections. The crystal consists of layers of hydrogen-bonded cations, [HN(CH2CH2OH)(3)](+) and anions, Br-. Within a layer every cation donates and every anion accepts three hydrogen bonds. In the cation, trifurcated intramolecular hydrogen bonds are formed due to the surrounding of the hydrogen atom bonded to the N atom by the 2-hydroxyethyl groups.
引用
收藏
页码:69 / 73
页数:5
相关论文
共 50 条
  • [41] CRYSTAL-STRUCTURE OF N-(2-HYDROXYETHYL)-OCTADECANAMIDE
    DAHLEN, B
    PASCHER, I
    SUNDELL, S
    ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1977, 31 (04): : 313 - 320
  • [42] REACTIONS OF HYDROXIDE TETRAKIS(2-HYDROXYETHYL)AMMONIUM
    DOUMAUX, AR
    BARNES, RK
    JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (20): : 3630 - 3632
  • [43] Crystal and molecular structure of N-methyl-bis(2-hydroxyethyl)ammonium (4-chlorphenylsulfonyl)acetate
    M. G. Voronkov
    V. S. Fundamenskii
    S. N. Adamovich
    È. A. Zel’bst
    A. A. Kashaev
    V. A. Brouskov
    R. G. Mirskov
    A. N. Mirskova
    Journal of Structural Chemistry, 2013, 54 : 182 - 185
  • [44] Crystal and molecular structure of N-methyl-bis(2-hydroxyethyl)ammonium (4-chlorphenylsulfonyl)acetate
    Voronkov, M. G.
    Fundamenskii, V. S.
    Adamovich, S. N.
    Zel'bst, E. A.
    Kashaev, A. A.
    Brouskov, V. A.
    Mirskov, R. G.
    Mirskova, A. N.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 54 (01) : 182 - 185
  • [45] Synthesis, crystal structure determination and antimicrobial studies of copper(II) picrate complexes with N,N,N′,N"-tetrakis(2-hydroxyethyl/propyl) ethylenediamine and tris(2-hydroxyethyl)amine
    Kumar, R.
    Obrai, S.
    Kaur, A.
    Hundal, G.
    Meehnian, H.
    Jana, A. K.
    POLYHEDRON, 2013, 56 : 55 - 61
  • [46] Bis(2-hydroxyethyl)ammonium 2-bromophenolate
    Padayachy, Kamentheren
    Fernandes, Manuel A.
    Marques, Helder M.
    Lemmerer, Andreas
    de Sousa, Alvaro S.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2610 - +
  • [47] KINETIC STUDIES ON DECOMPOSITION OF TRIS(2-HYDROXYETHYL) ISOCYANURATE
    KOYAMA, T
    ISHIKAWA, T
    YAMAZAKI, Y
    NIPPON KAGAKU KAISHI, 1975, (03) : 477 - 480
  • [48] Ferroelectric properties in metal-coordinated complex tris(2-hydroxyethyl) ammonium trichloro cadmium(II)
    Tang, Zheng
    Sun, Xiao-Fan
    Gao, Zhang-Ran
    Li, Dong
    Jiao, Shu-Lin
    Xu, Cui-Ping
    Tang, Wen-Chao
    Yang, Zhu
    Chen, Peng
    Xu, Yan-Ming
    Xu, Jinlong
    Cai, Hong-Ling
    Wu, X. S.
    JOURNAL OF MATERIALS CHEMISTRY C, 2022, 10 (06) : 2255 - 2262
  • [49] Quantum-Chemical Study of Reaction Mechanism between Tris(2-hydroxyethyl)ammonium Fluoride and Tetraethoxysilane
    Shagun, V. A.
    Voronkov, M. G.
    Vrazhnov, D. V.
    Kochina, T. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2011, 81 (09) : 1792 - 1797
  • [50] Quantum-chemical study of reaction mechanism between tris(2-hydroxyethyl)ammonium fluoride and tetraethoxysilane
    V. A. Shagun
    M. G. Voronkov
    D. V. Vrazhnov
    T. A. Kochina
    Russian Journal of General Chemistry, 2011, 81 : 1792 - 1797