Kinetics and mechanisms of formation and reactivity of non-heme iron oxygen intermediates

被引：324
|
作者：
Kryatov, SV
Rybak-Akimova, EV
Schindler, S
机构：
[1] Univ Giessen, Inst Anorgan & Analyt Chem, D-35392 Giessen, Germany
[2] Tufts Univ, Dept Chem, Medford, MA 02155 USA
来源：
CHEMICAL REVIEWS | 2005年 / 105卷 / 06期
关键词：
D O I：
10.1021/cr030709z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An overview of the formation and reactivity of non-heme iron oxygen intermediates is given. The binding of dioxygen to the non-heme biocomplexes bleomycin and hemerythrin and to iron enzymes is covered. Furthermore, model complexes of non-heme mononuclear and dinuclear iron complexes and their interaction with dioxygen, superoxide, and hydrogen peroxide are also considered.
引用
收藏
页码：2175 / 2226
页数：52
相关论文
共 50 条
  • [1] Oxygen intermediates in mononuclear non-heme iron sites: Electronic structure and reactivity.
    Decker, A
    Solomon, EI
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U1510 - U1510
  • [2] Kinetics and mechanisms of oxygen and peroxide activation with non-heme iron enzyme models
    Rybak-Akimova, Elena
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [3] Electronic structure of activated bleomycin: Oxygen intermediates in heme versus non-heme iron
    Neese, F
    Zaleski, JM
    Zaleski, KL
    Solomon, EI
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (47) : 11703 - 11724
  • [4] Intermediates in non-heme iron dioxygenase catalysis.
    Lipscomb, JD
    Orville, AM
    Frazee, RW
    Ohlendorf, DH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 698 - INOR
  • [5] Reactive intermediates in binuclear non-heme iron catalyzed oxygen atom transfer reactions
    Rogge, CE
    Caradonnna, JP
    JOURNAL OF INORGANIC BIOCHEMISTRY, 1999, 74 (1-4) : 280 - 280
  • [6] Reactive intermediates in binuclear non-heme iron catalyzed oxygen atom transfer reactions
    Caradonna, JP
    Spuches, AM
    Rogge, C
    Foster, T
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2001, 86 (01) : 168 - 168
  • [7] Direct reactivity studies of non-heme iron-oxo intermediates toward alkane oxidation
    Zima, Alexandra M.
    Lyakin, Oleg Y.
    Bryliakov, Konstantin P.
    Talsi, Evgenii P.
    CATALYSIS COMMUNICATIONS, 2018, 108 : 77 - 81
  • [8] Reaction mechanisms of mononuclear non-heme iron oxygenases
    Abu-Omar, MM
    Loaiza, A
    Hontzeas, N
    CHEMICAL REVIEWS, 2005, 105 (06) : 2227 - 2252
  • [9] Oxygen activation by mononuclear non-heme iron proteins
    Nivorozhkin, AL
    Girerd, JJ
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (06): : 609 - 611
  • [10] Mitochondrial reactive oxygen species and heme, non-heme iron metabolism
    Ito, Hiromu
    Kurokawa, Hiromi
    Matsui, Hirofumi
    ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 2021, 700
12345