AsCat and FurCat: new Pd catalysts for selective room-temperature Stille cross-couplings of benzyl chlorides with organostannanes

被引：19

作者：

Ronson, Thomas O. ^{[1
]}

Carney, Jonathan R. ^{[1
]}

Whitwood, Adrian C. ^{[1
]}

Taylor, Richard J. K. ^{[1
]}

Fairlamb, Ian J. S. ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 16期

基金：

英国工程与自然科学研究理事会;

关键词：

BROMIDES; LIGANDS; HALIDES; ARYL; COMPLEXES; DERIVATIVES; EFFICIENT; REAGENTS; ACID;

D O I：

10.1039/c4cc09810b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel succinimide-based palladium complexes, AsCat and FurCat, are highly efficient catalysts for room-temperature Stille cross-coupling of organostannanes with benzyl chlorides. The air- and moisture-stable catalysts are prepared in one step, and the coupling reactions proceed with a high selectivity for the benzyl position under mild conditions without the need for additives.

引用

页码：3466 / 3469

页数：4

共 29 条

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