Dichlorooxo(quinoline-8-thiolato-κ2N,S)(triphenylphosphine oxide-κO)rhenium(V) acetone solvate

被引：1
|
作者：
Miyashita, Y [1 ]
Ohashi, T [1 ]
Imai, A [1 ]
Amir, N [1 ]
Fujisawa, K [1 ]
Okamoto, K [1 ]
机构：
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷
关键词：
D O I：
10.1107/S0108270105027770
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The complex molecule in the title compound, [Re(C9H 6NS)-Cl2O(C18H15OP)]·C 3H6O, has distorted octahedral geometry. The Re=O bond occupies the position trans to the triphenylphosphine oxide O atom. The Re-Cl bond trans to the thiolate S atom is longer than that trans to the quinoline N atom, implying a stronger trans influence of the S atom. Intra- and intermolecular π-π interactions are also observed between the π rings in the complex. © 2005 International Union of Crystallography.
引用
收藏
页码：M476 / M478
页数：3
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