High-throughput synthesis of new Ni(II), Pd(II), and Co(II) catalysts and polymerization of norbornene utilizing the self-made parallel polymerization reactor system

被引：20

作者：

Cho, HY

Hong, DS

Jeong, DW

Gong, YD

Woo, SI

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Taejon 305701, South Korea

[2] Korea Adv Inst Sci & Technol, CUPS, Taejon 305701, South Korea

[3] Korea Res Inst Chem Technol, Div Bioorgan, Taejon 305600, South Korea

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 01期

关键词：

catalysts; high-throughput synthesis; parallel polymerization reactor system; transition metal chemistry; vinyl-type polynorbornene;

D O I：

10.1002/marc.200300158

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report the development of new Ni(II), Pd(II), and Co(II) catalysts containing ligands of pyrazolylpyridine derivatives by combinatorial and high-throughput synthesis technology. Vinyl type polynorbornene was polymerized utilizing the self-made parallel polymerization reactor system. The Ni(II) catalyst 1 has a polymerization activity of 266.7 kg(polymer) . mol(cat)(-1) . h(-1). We introduce a fast way to conduct catalyst synthesis and high-throughput screening for polymerization.

引用

页码：302 / 306

页数：5

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