High-throughput synthesis of new Ni(II), Pd(II), and Co(II) catalysts and polymerization of norbornene utilizing the self-made parallel polymerization reactor system

被引：20
|
作者：
Cho, HY
Hong, DS
Jeong, DW
Gong, YD
Woo, SI
机构：
[1] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, CUPS, Taejon 305701, South Korea
[3] Korea Res Inst Chem Technol, Div Bioorgan, Taejon 305600, South Korea
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 01期
关键词：
catalysts; high-throughput synthesis; parallel polymerization reactor system; transition metal chemistry; vinyl-type polynorbornene;
D O I：
10.1002/marc.200300158
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We report the development of new Ni(II), Pd(II), and Co(II) catalysts containing ligands of pyrazolylpyridine derivatives by combinatorial and high-throughput synthesis technology. Vinyl type polynorbornene was polymerized utilizing the self-made parallel polymerization reactor system. The Ni(II) catalyst 1 has a polymerization activity of 266.7 kg(polymer) . mol(cat)(-1) . h(-1). We introduce a fast way to conduct catalyst synthesis and high-throughput screening for polymerization.
引用
收藏
页码：302 / 306
页数：5
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