Synthesis of Benzonitrile from Dinitrogen

被引：21

作者：

Klopsch, Isabel ^{[1
]}

Schendzielorz, Florian ^{[1
]}

Volkmann, Christian ^{[1
]}

Wuertele, Christian ^{[1
]}

Schneider, Sven ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, Tammannstr 4, D-37077 Gottingen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2018年 / 644卷 / 17期

基金：

欧洲研究理事会;

关键词：

Pincer ligand; Rhenium; Dinitrogen; Nitrile; N-2; splitting; CATALYTIC-REDUCTION; COMPLEXES BEARING; NITROGEN-FIXATION; CLEAVAGE; MOLYBDENUM; CONVERSION; AMMONIA; NITRIDE; FUNCTIONALIZATION; PERCHLORATE;

D O I：

10.1002/zaac.201800181

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The rhenium mediated synthesis of benzonitrile is reported with direct use of N-2 as a nitrogen source. The reaction affords benzonitrile in about 30% overall yield upon N-2 splitting and benzylation of resulting terminal nitride. Subsequent oxidation of an intermediate phenylketimido compound restores the parent rhenium complex within a full four-step synthetic cycle. The reaction shows that previously observed nitrile tautomerization is not a prerequisite for nitrile synthesis from N-2 with this system.

引用

页码：916 / 919

页数：4

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