Solvent-Free Synthesis of 1,8-Dioxo-octahydroxanthenes and 14-Aryl-14H-dibenzo[a,j]xanthenes using Saccharin Sulfonic Acid as an Efficient and Green Catalyst

被引：20
|
作者：
Zare, Abdolkarim [1 ]
Mokhlesi, Mohammad [2 ]
Hasaninejad, Alireza [3 ]
Hekmat-Zadeh, Tahereh [1 ]
机构：
[1] Payame Noor Univ, Dept Chem, Tehran, Iran
[2] Bu Ali Sina Univ, Fac Chem, Hamadan 6517838683, Iran
[3] Persian Gulf Univ, Fac Sci, Dept Chem, Bushehr 75169, Iran
来源：
E-JOURNAL OF CHEMISTRY | 2012年 / 9卷 / 04期
关键词：
1,8-Dioxo-octahydroxanthene; 14-Aryl-14H-dibenzo[a; j]xanthene; Saccharin sulfonic acid (SaSA); Sulfonic acid-containing catalyst; One-pot multi-component reaction; Solvent-free; SILICA SULFURIC-ACID; ONE-POT SYNTHESIS; HIGHLY EFFICIENT; IMIDAZOLIUM CHLORIDE; CONDENSATION; DERIVATIVES; HCLO4-SIO2; ALDEHYDES; PROTOCOL; SYSTEM;
D O I：
10.1155/2012/596862
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Saccharin sulfonic acid (SaSA) is utilized as a highly efficient, green and inexpensive sulfonic acid-containing catalyst for the following one-pot multi-component organic transformations: (i) the condensation of dimedone (2 eq.) with aromatic aldehydes (1 eq.) leading to 1,8-dioxo-octahydroxanthenes, and (ii) the reaction of 2-naphthol (2 eq.) with arylaldehydes (1 eq.) leading to 14-aryl-14H-dibenzo[a,j]xanthenes. In these protocols, the title compounds are produced in high to excellent yields and in relatively short reaction times under solvent-free conditions.
引用
收藏
页码：1854 / 1863
页数：10
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