Transition-metal-free highly chemo- and regioselective arylation of unactivated arenes with aryl halides over recyclable heterogeneous catalysts

被引:94
|
作者
Liu, Hongli [1 ]
Yin, Biaolin [1 ]
Gao, Zhiqiang [1 ]
Li, Yingwei [1 ]
Jiang, Huanfeng [1 ]
机构
[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
关键词
ORGANIC FRAMEWORK; COUPLING REACTIONS; NANOPARTICLES; HETEROCYCLES; ACTIVATION; CHLORIDES; BUTOXIDE; BENZENE; PROMOTE;
D O I
10.1039/c2cc16790e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel heterogeneous catalysis system using metal-organic frameworks as catalyst demonstrated excellent chemo- and regioselectivity for the direct arylation of unactivated arenes with aryl iodides/bromides without the assistance of any transition metals.
引用
收藏
页码:2033 / 2035
页数:3
相关论文
共 50 条
  • [31] Synthesis of Dibenzosultams by "Transition-Metal-Free" Photoinduced Intramolecular Arylation of N-Aryl-2-halobenzenesulfonamides
    Guerra, Walter D.
    Rossi, Roberto A.
    Pierini, Adriana B.
    Barolo, Silvia M.
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2016, 81 (12): : 4965 - 4973
  • [32] Directionally Aligned Crown Ethers as Superactive Organocatalysts for Transition-metal Ion-free Arylation of Unactivated Arenes
    Li, Zhaojie
    Shen, Jie
    Jiang, Qing
    Shen, Sheng
    Zhou, Jing
    Zeng, Huaqiang
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2022, 17 (15)
  • [33] Facile, regioselective oxidative selenocyanation of N-aryl enaminones under transition-metal-free conditions
    Sorabad, Ganesh Shivayogappa
    Maddani, Mahagundappa Rachappa
    [J]. NEW JOURNAL OF CHEMISTRY, 2020, 44 (06) : 2222 - 2227
  • [34] Transition-metal-free, oxidative C(sp3)-H arylation of amides with zeolite catalysts
    Vercammen, Jannick
    Krasniqi, Besir
    De Vos, Dirk
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2023, 13 (21) : 6274 - 6280
  • [35] Transition-Metal-Free Multicomponent Approach to the Regioselective Synthesis of Highly Substituted N-Alkylpyrazoles
    Ali, Kasim
    Panda, Gautam
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2023, 18 (04)
  • [36] Transition metal-free and base-mediated transformation arylation of unactivated benzene with aryl halides in presence of N,N′-bis(salicylidene) ethylenediamine as organocatalyst
    Ghonchepour, Ehsan
    Islami, Mohammad Reza
    Mostafavi, Hamid
    Tikdari, Ahmad Momeni
    Sheikhshoaie, Iran
    [J]. CATALYSIS COMMUNICATIONS, 2018, 107 : 87 - 91
  • [37] Nucleophilic Addition versus SNAr Study: Chemo-, Regio- and Stereoselective Hydrothiolation of Haloaryl Alkynes over S-Arylation of Aryl Halides
    Patel, Monika
    Saunthwal, Rakesh K.
    Dhaked, Devendra K.
    Bharatam, Prasad V.
    Verma, Akhilesh K.
    [J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2015, 4 (09) : 894 - 898
  • [38] Direct Oxidation of Methane to Methanol over Transition-Metal-Free Ferrierite Zeolite Catalysts
    Xiao, Peipei
    Wang, Yong
    Lu, Yao
    Nakamura, Kengo
    Ozawa, Nobuki
    Kubo, Momoji
    Gies, Hermann
    Yokoi, Toshiyuki
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (14) : 10014 - 10022
  • [39] Tetramethylammonium Fluoride Tetrahydrate-Mediated Transition Metal-Free Coupling of Aryl Iodides with Unactivated Arenes in Air
    Nozawa-Kumada, Kanako
    Nakamura, Kosuke
    Kurosu, Satoshi
    Iwakawa, Yuki
    Denneval, Charline
    Shigeno, Masanori
    Kondo, Yoshinori
    [J]. CHEMICAL & PHARMACEUTICAL BULLETIN, 2019, 67 (10) : 1042 - 1045
  • [40] A high-throughput experimentation study of the epoxidation of alkenes with transition-metal-free heterogeneous catalysts
    Pescarmona, Paolo P.
    Jacobs, Pierre A.
    [J]. CATALYSIS TODAY, 2008, 137 (01) : 52 - 60