Novel Zn(II) coordination polymer based on 1,2-bis (4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

被引：1

作者：

Wang, Huaishan ^{[1
]}

Szeto, Lap ^{[2
]}

Chan, Wesley Ting Kwok ^{[1
]}

Yeung, Ho-Lun ^{[1
]}

Wong, Ka-Leung ^{[3
]}

Wong, Wing-Tak ^{[1
]}

机构：

[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China

[2] Univ Hong Kong, Dept Chem, Pokfulam, Hong Kong, Peoples R China

[3] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2012年 / 90卷 / 01期

关键词：

metal organic framework; coordination polymer; 1,2-bis(4-pyridyl)hydrazine; interpenetrating polymer; microporous; hydrogen bond; CRYSTAL-STRUCTURES; HYDRAZO COMPOUNDS; TRANSFER HYDROGENATION; AZO-COMPOUNDS; RANEY-NICKEL; COMPLEXES; AZOBENZENE; EXCHANGE;

D O I：

10.1139/V11-132

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two MOFs were reported based on Zn(H) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn-2(L1)(2)(L2)(2)](infinity) was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn-2(L1)(2)(L3)(2)](infinity), was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF H consists of large porosity with a total volume of 3746 angstrom(3) that occupies 34.1% of the unit cell.

引用

页码：100 / 107

页数：8

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