A polyhedral metal-organic framework based on rigid precursor for photocatalytic properties

被引：11
|
作者：
Wang, Fumin [1 ]
Liu, Weicong [2 ]
Li, Saying [1 ]
Gable, Robert W. [3 ]
Zhong, Huarui [2 ]
Xu, Qiuxia [2 ]
Huang, Gaoxiang [2 ]
Singh, Amita [4 ]
Liu, Jianqiang [2 ]
Kumar, Abhinav [4 ]
机构：
[1] Shaanxi Xueqian Normal Univ, Dept Chem & Chem Engn, Xian, Shaanxi, Peoples R China
[2] Guangdong Med Univ, Sch Pharm, Key Lab Res & Dev New Med Mat, Dongguan Key Lab Drug Design & Formulat Technol, Dongguan 523808, Peoples R China
[3] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia
[4] Univ Lucknow, Dept Chem, Fac Sci, Lucknow 226007, Uttar Pradesh, India
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2018年 / 97卷
关键词：
Tetracarboxylate; Photocatalysis; Calculation; CU(I) COORDINATION POLYMER; BIS-AMIDE LIGANDS; 001 ACTIVE FACETS; HIGH-PERFORMANCE; METHYL VIOLET; CO2; REDUCTION; DEGRADATION; NITROAROMATICS; DESIGN; ZN(II);
D O I：
10.1016/j.inoche.2018.09.025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A 3D polyhedral metal organic framework, [Cu-4(L)(2)(H2O)(4).5DMF](n) (1) (H4L = 3,5-di(3,5-dicarboxyphenyl)nitrobenzene), has been designed and successfully synthesized. 1 shows a 3D mfj topological framework with 1D triangular channels. The UV diffuse reflectance spectroscopy of the MOF indicates its semiconducting nature which induces photocatalytic property in the MOF. The photocatalytic property of 1 in photo-degradation of organic dyes viz. methyl violet and Rhodamine B have been investigated. The possible mechanism for the photocatalytic activity of 1 against organic dyes has been addressed using density of states (DOS) and partial DOS (pDOS) calculations.
引用
收藏
页码：109 / 112
页数：4
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