Gold enhanced spectroelectrochemical investigation of 2-mercaptobenzothiazole, isopropyl xanthate and butylethoxycarbonylthiourea adsorption on minerals
flotation collectors;
sulphide ores;
mineral processing;
redox reactions;
D O I:
10.1016/j.mineng.2007.02.003
中图分类号:
TQ [化学工业];
学科分类号:
0817 ;
摘要:
The interaction of the flotation collectors 2-mercaptobenzotbiazole, potassium isopropyl xanthate and butylethoxyearbonylthiourea with chalcopyrite, chalcocite, pyrite and galena has been investigated using surface enhanced Raman scattering (SERS) spectroscopy. For metals and minerals, adsorption occurs via charge transfer to form a metal-sulfur bond and, in situations for which the reversible potential of the formation of the bulk phase is known, at underpotentials to the reversible compound formation. (C) 2007 Elsevier Ltd. All rights reserved.
机构:
Faculty of Chemistry and Chemical Engineering, University of Maribor, SloveniaFaculty of Chemistry and Chemical Engineering, University of Maribor, Slovenia
Finšgar, Matjaž
Čakara, Duško
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机构:
Department of Biotechnology, University of Rijeka, Croatia
Center for Micro and Nano Sciences and Technologies, University of Rijeka, CroatiaFaculty of Chemistry and Chemical Engineering, University of Maribor, Slovenia
机构:
Tata Consultancy Serv Ltd, TCS Res, Phys Sci Res Area, 54-B,Hadapsar Ind Estate, Pune 411013, Maharashtra, IndiaTata Consultancy Serv Ltd, TCS Res, Phys Sci Res Area, 54-B,Hadapsar Ind Estate, Pune 411013, Maharashtra, India
Kumar, Dharmendr
Srinivasan, Sriram Goverapet
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TCS Res, Tata Consultancy Serv Ltd, Phys Sci Res Area, Block A,2Nd Floor,IITM-Res Pk,Kanagam Rd, Chennai 600113, Tamil Nadu, IndiaTata Consultancy Serv Ltd, TCS Res, Phys Sci Res Area, 54-B,Hadapsar Ind Estate, Pune 411013, Maharashtra, India
Srinivasan, Sriram Goverapet
Jain, Vinay
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机构:
Tata Consultancy Serv Ltd, TCS Res, Phys Sci Res Area, 54-B,Hadapsar Ind Estate, Pune 411013, Maharashtra, IndiaTata Consultancy Serv Ltd, TCS Res, Phys Sci Res Area, 54-B,Hadapsar Ind Estate, Pune 411013, Maharashtra, India
Jain, Vinay
Rai, Beena
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机构:
Tata Consultancy Serv Ltd, TCS Res, Phys Sci Res Area, 54-B,Hadapsar Ind Estate, Pune 411013, Maharashtra, IndiaTata Consultancy Serv Ltd, TCS Res, Phys Sci Res Area, 54-B,Hadapsar Ind Estate, Pune 411013, Maharashtra, India