Synthesis and Optical Properties of Fluorinated Tetraphenylethylenes

被引：4
|
作者：
Zhang, Zhenglin [1 ]
Lieu, Thien [1 ]
Wang, Xiqu [1 ]
Daugulis, Olafs [1 ]
Miljanic, Ognjen S. [1 ]
机构：
[1] Univ Houston, Dept Chem, 3585 Cullen Blvd 112, Houston, TX 77204 USA
来源：
CHEMPHOTOCHEM | 2022年 / 6卷 / 05期
基金：
美国国家科学基金会;
关键词：
copper; C-C coupling; fluorination; phenanthrene; palladium; photocyclization; AGGREGATION-INDUCED EMISSION; PHOTOCYCLIZATION; DERIVATIVES; RESTRICTION; MECHANISM; BOND;
D O I：
10.1002/cptc.202200011
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Four extensively fluorinated tetraphenylethylenes (TPE) and one extensively fluorinated triphenylethylene have been synthesized using combinations of copper-catalyzed C-H functionalization reactions and Stille coupling reactions. Surprisingly, in contrast to the parent TPE, these compounds show little to no aggregation-induced emission (AIE). Instead, photocyclization into fluorinated phenanthrene products occurs. Effects of solvent and oxygen on the yield and selectivity of this photo-cyclization have been examined.
引用
收藏
页数：5
相关论文
共 50 条
  • [21] Synthesis of a fluorinated photoresist for optical waveguide devices
    Xu Fei
    Ying Wan
    Haiming Zhang
    Zhanchen Cui
    Daming Zhang
    Applied Physics A, 2009, 96 : 467 - 472
  • [22] SYNTHESIS, STRUCTURE AND PROPERTIES OF FLUORINATED GRAPHITE
    NAKAJIMA, T
    MACROMOLECULAR SYMPOSIA, 1994, 82 : 19 - 32
  • [23] Synthesis of a fluorinated photoresist for optical waveguide devices
    Fei, Xu
    Wan, Ying
    Zhang, Haiming
    Cui, Zhanchen
    Zhang, Daming
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2009, 96 (02): : 467 - 472
  • [24] SYNTHESIS AND PROPERTIES OF SOME FLUORINATED KETONES
    PARK, JD
    NOBLE, RE
    LACHER, JR
    JOURNAL OF ORGANIC CHEMISTRY, 1958, 23 (09): : 1396 - 1398
  • [25] SYNTHESIS AND PROPERTIES OF NEW FLUORINATED SURFACTANTS
    CAMBON, A
    SZONYI, S
    SZONYI, F
    JOURNAL OF FLUORINE CHEMISTRY, 1985, 29 (1-2) : 83 - 83
  • [26] Synthesis and spectral properties of fluorinated α,β-epoxyphosphonates
    Rapp, Magdalena
    Margas-Musielak, Klaudia
    Koroniak, Henryk
    JOURNAL OF FLUORINE CHEMISTRY, 2015, 179 : 142 - 149
  • [27] SYNTHESIS AND PROPERTIES OF HIGHLY FLUORINATED POLYIMIDES
    HOUGHAM, G
    TESORO, G
    SHAW, J
    MACROMOLECULES, 1994, 27 (13) : 3642 - 3649
  • [28] Synthesis and surface properties of fluorinated polyurethanes
    Kim, HJ
    POLYMER-KOREA, 2001, 25 (01) : 33 - 40
  • [29] Fluorinated DNA Micelles: Synthesis and Properties
    Zou, Jianmei
    Jin, Cheng
    Wang, Ruowen
    Kuai, Hailan
    Zhang, Lili
    Zhang, Xiaobing
    Li, Juan
    Qiu, Liping
    Tan, Weihong
    ANALYTICAL CHEMISTRY, 2018, 90 (11) : 6843 - 6850
  • [30] Synthesis and surface properties of a fluorinated polyether
    Gan, DJ
    Cao, WJ
    Wang, ZJ
    JOURNAL OF FLUORINE CHEMISTRY, 2002, 116 (01) : 59 - 63
12345