Simple and fast fabrication of polymer template-Ru composite as a catalyst for hydrogen generation from alkaline NaBH4 solution

被引：92

作者：

Hsueh, Chan-Li ^{[1
]}

Chen, Chuh-Yung ^{[2
]}

Ku, Jie-Ren ^{[1
]}

Tsai, Shing-Fen ^{[1
]}

Hsu, Ya-Yi ^{[1
]}

Tsau, Fanghei ^{[1
]}

Jeng, Ming-Shan ^{[1
]}

机构：

[1] ITRI, EEL, Hsinchu 310, Taiwan

[2] Natl Cheng Kung Univ, Dept Chem Engn, Tainan 701, Taiwan

来源：

JOURNAL OF POWER SOURCES | 2008年 / 177卷 / 02期

关键词：

hydrogen generation; polymer template-ru composite; catalyst; NaBH4;

D O I：

10.1016/j.jpowsour.2007.11.096

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polymer template-Ru composite (Ru/IR-120) catalyst was prepared using a simple and fast method for generating hydrogen from an aqueous alkaline NaBH4 solution. The hydrogen generation rate was determined as a function of solution temperature, NaBH4 concentration, and NaOH (a base-stabilizer) concentration. The maximum hydrogen generation rate reached 132 ml min(-1) g(-1) catalyst at 298 K, using a Ru/IR-120 catalyst that contained only 1 wt.% Ru. The catalyst exhibits a quick response and good durability during the hydrolysis of alkaline NaBH4 solution. The activation energy for the hydrogen generation reaction was determined to be 49.72 kJ mol(-1). (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：485 / 492

页数：8

共 50 条

[41] Hydrogen Generation from NaBH4 Solution with the High-performance Co(0) Catalyst Using a Cold Plasma Method
Sahin, O.
Hansu, F.
Saka, C.
Baytar, O.
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2014, 36 (14) : 1578 - 1587
[42] Ni/Ag/silica nanocomposite catalysts for hydrogen generation from hydrolysis of NaBH4 solution
Chen, Yingbo
Kim, Hern
MATERIALS LETTERS, 2008, 62 (8-9) : 1451 - 1454
[43] Highly dispersed Ru/Co catalyst with enhanced activity for catalyzing NaBH4 hydrolysis in alkaline solutions
Zhang, Jiapeng
Lin, Fanzhen
Yang, Lijing
Dong, Hua
CHINESE CHEMICAL LETTERS, 2020, 31 (09) : 2512 - 2515
[44] Highly dispersed Ru/Co catalyst with enhanced activity for catalyzing NaBH4 hydrolysis in alkaline solutions
Jiapeng Zhang
Fanzhen Lin
Lijing Yang
Hua Dong
Chinese Chemical Letters, 2020, 31 (09) : 2512 - 2515
[45] Highly efficient acid-treated cobalt catalyst for hydrogen generation from NaBH4 hydrolysis
Akdim, O.
Demirci, U. B.
Miele, P.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (11) : 4780 - 4787
[46] A stable Ni-B catalyst in hydrogen generation via NaBH4 hydrolysis
Lee, Jae Kwang
Ann, Hyang-hwa
Yi, Youngmi
Lee, Kyu Wan
Uhm, Sunghyun
Lee, Jaeyoung
CATALYSIS COMMUNICATIONS, 2011, 16 (01) : 120 - 123
[47] Aerogel of chitosan/graphene oxide loaded Ru-CoP as a monolithic catalyst for hydrogen generation via NaBH4 hydrolysis
Wang, Chenchen
Cheng, Lei
Ye, Si
Yan, Puxuan
Sun, Lixian
JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 952
[48] Fabrication and Catalytic Activity of Pt/Ni/Fe Trimetallic Nanoparticles for Hydrogen Generation from NaBH4
Li Wenqi
Zhao Wanguo
Zhou Xingyun
Su Li
Zhang Haijun
Lu Lilin
Zhang Shaowei
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2014, 35 (10): : 2164 - 2169
[49] Porous Co-P-Pd nanotube arrays for hydrogen generation by catalyzing the hydrolysis of alkaline NaBH4 solution
Wang, Shuhai
Fan, Yanan
Chen, Minqi
Xie, Yanyu
Wang, Dawei
Su, Cheng-Yong
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (16) : 8250 - 8255
[50] Effects of organic acid catalysts on the hydrogen generation from NaBH4
Go Young Moon
Sang Seo Lee
Ga Ram Yang
Kwang Ho Song
Korean Journal of Chemical Engineering, 2010, 27 : 474 - 479

← 1 2 3 4 5 →