H2O-D2O exchange in lawsonite

被引:0
|
作者
Marion, S
Meyer, HW
Carpenter, M
Norby, T
机构
[1] Univ Oslo, Dept Chem, Ctr Mat Sci, N-0349 Oslo, Norway
[2] Univ Cambridge, Dept Earth Sci, Cambridge CB2 3EQ, England
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中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
The mineral lawsonite, CaAl2Si2O7(OH)(2).H2O, was deuterated to about 93% in a thermobalance by H2O-D2O gas-phase exchange at temperatures between 375 and 425 degreesC. The kinetics of this reaction are reported and diffusion coefficients for the H2O-D2O exchange are calculated from thermogravimetric measurements.
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页码:1166 / 1169
页数:4
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