Synthesis of a Versatile Pentacyclic Building Block for Organic Electronics

被引：1

作者：

McDearmon, Brenden ^{[1
,2
]}

Lim, Eunhee ^{[1
]}

O'Hara, Kathryn ^{[1
]}

Nakayama, Hidenori ^{[1
,3
]}

Luo, Yingdong ^{[4
]}

Chabinyc, Michael L. ^{[1
]}

Hawker, Craig J. ^{[1
,2
,4
]}

机构：

[1] Univ Calif Santa Barbara, Mat Dept, Santa Barbara, CA 93106 USA

[2] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[3] Mitsubishi Chem Grp Sci & Technol Res Ctr Inc, Aoba Ku, 1000 Kamoshida Cho, Yokohama, Kanagawa 2278502, Japan

[4] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2017年 / 55卷 / 16期

基金：

美国国家科学基金会;

关键词：

conjugated polymers; copolymers; organic electronics; polycyclic building blocks; redox polymers; POLYMER SOLAR-CELLS; CONJUGATED POLYMERS; SEMICONDUCTING POLYMERS; HIGH-PERFORMANCE; TRANSISTORS; BENZOQUINONE; COPOLYMERS; AMBIPOLAR;

D O I：

10.1002/pola.28656

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new pentacyclic building block, benzodibenzofuranquinone (BDBFQ), is synthesized in a single step from the inexpensive and readily available feedstocks chloranil and 3bromophenol. This versatile repeat unit is incorporated into a series of conjugated materials as either the redox active quinone form or as an electron-rich dialkylated benzodibenzofuran (BDBF) unit. To illustrate the performance that can be obtained from these systems, optical and electrochemical properties were studied via UV-vis-NIR spectroscopy and cyclic voltammetry. Thin-film morphology was characterized via grazing incidence wide-angle X-ray scattering with thin-film fieldeffect transistor measurements further demonstrating the utility of this system. (C) 2017 Wiley Periodicals, Inc.

引用

页码：2618 / 2628

页数：11

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