Structure and photoluminescence of cubane-like [Cu4I4] cluster-based 1D coordination polymer assembled with bis(triazole)pyridine ligand

被引：7

作者：

Bai, Shi-Qiang ^{[1
]}

Ke, Karen Lin ^{[1
]}

Young, David James ^{[1
,2
]}

Hor, T. S. Andy ^{[1
,3
]}

机构：

[1] ASTAR, Inst Mat Res & Engn, 2 Fusionopolis Way,Innovis 08-03, Singapore 138634, Singapore

[2] Univ Sunshine Coast, Fac Sci Hlth Educ & Engn, Maroochydore, Qld 4558, Australia

[3] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 849-850卷

关键词：

Bis(triazole) ligand; Cubane-like [Cu4I4] cluster; Coordination polymer; Luminescence; COPPER(I) IODIDE; LUMINESCENCE PROPERTIES; TERMINAL ALKYNES; COMPLEXES; THERMOCHROMISM; CONSTRUCTION; EMISSION; AZIDES; NET;

D O I：

10.1016/j.jorganchem.2017.03.040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[L2Cu4I4](n) (1) based on a cubic [Cu4I4] node and ditopic, bridging bis(triazole) (L = 2,6-bis((1H-1,2,3-triazol-1-yl)methyl)pyridine) is a unique and highly symmetric cubane cluster based coordination polymer with strong yellow emission. Comparison with similar coordination polymers permits a structure activity relationship and reveals that the emission energy for these [Cu4I4] cluster-based materials occurs in the mid-range of Cu center dot center dot center dot Cu distances and tetrahedral geometry index values. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：137 / 141

页数：5

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