Synthesis and properties of a Cu4(SCN)4 cubane cluster-based coordination polymer with a diamond net

被引：8
|
作者：
Ren, Shi-Bin [1 ,2 ]
Zhou, Le [1 ]
Zhang, Jun [1 ]
Li, Cheng-Hui [1 ]
Li, Yi-Zhi [1 ]
Du, Hong-Bin [1 ]
You, Xiao-Zeng [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Taizhou Univ, Sch Pharmaceut & Chem Engn, Taizhou 317000, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 04期
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; CuSCN; Cubane cluster; Diamond net; Photoluminescence; TO-CRYSTAL TRANSFORMATION; PHOTOLUMINESCENCE; SOLIDS; FRAMEWORKS; COMPLEXES; ISOMERISM; ADDUCTS; COPPER; BR; CL;
D O I：
10.1016/j.inoche.2011.01.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A triply-interpenetrating diamondoid coordination polymer [Cu-4(SCN)(4)(tpom)]center dot 2H(2)O (1, tpom = tetrakis (4-pyridyloxymethylene)methane) was prepared, which is built from an unprecedented pseudohalide cubane cluster Cu-4(SCN)(4) and tetrahedral tpom ligand. 1 exhibits high thermal stability and temperature-dependent photoluminescence behaviors resembling those of Cu4Cl4 complexes. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：558 / 561
页数：4
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