μ-2,2′,6,6′-Tetramethyl-4,4′-bipyridine-κ2N1:N1′-bis[(diethylenetriamine-κ3N,N′,N")palladium(II)] tetranitrate

被引：1

作者：

Seidel, Ruediger W. ^{[1
]}

Oppel, Iris M. ^{[2
]}

机构：

[1] Lehrstuhl Analyt Chem, D-44780 Bochum, Germany

[2] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52074 Aachen, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2011年 / 67卷

关键词：

PILLARED COORDINATION CAGES; DISCRETE STACKING; COMPLEXES; 4,4'-BIPYRIDINE; SUBSTITUTION; MOLECULES; PD;

D O I：

10.1107/S0108270111017586

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Pd-2(C4H13N3)(2)(C14H16N2)](NO3)(4), comprises discrete tetracationic dumbbell-type dinuclear complex molecules and noncoordinating nitrate anions. Two Pd(dien)(2+) moieties (dien is diethylenetriamine) are joined by the rigid linear exo-bidentate bridging 2,2',6,6'-tetramethyl-4,4'-bipyridine ligand to form the dinuclear complex, which lies across a centre of inversion in the space group P2(1)/n, so that the rings in the 2,2',6,6'-tetramethyl-4,4'-bipyridine bridging ligand are parallel. In the crystal, the primary and secondary amino groups of the dien ligand act as hydrogen-bond donors towards the nitrate anions to form a three-dimensional hydrogen-bond network.

引用

页码：M199 / M201

页数：3

共 50 条

[41] [6,6′-Bis(benzimidazol-2-yl-N3) -2,2′-bipyridine]dichlorocobalt(II)-dimethylformamide (1/2)
Cheng, K.-L.
Sheu, S.-C.
Lee, G.-H.
Lin, Y.-C.
Wang, Y.
Ho, T.-I.
Acta Crystallographica, Section C: Crystal Structure Communications, 1998, C53 (Pt 9): : 1238 - 1240
[42] Dichloro(4,4′-dinonyl-2,2′-bipyridine-κ2N,N′)platinum(II)
Kato, M
Ikemori, M
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2003, 59 : M25 - M26
[43] Dibenzoato-κO;κ2O,O′-(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)zinc(II)-benzoicacid (1/1)
Yao, Li
Li, Wen-Juan
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1408 - U1513
[44] (4′-Ferrocenyl-2,2′:6′,2"-terpyridine-κ3N1,N1′,N1")(1,10-phenanthroline-κ2N,N′)zinc(II) bis(perchlorate) acetonitrile monosolvate
Tang, Si-Ping
Kuang, Dai-Zhi
Feng, Yong-Lan
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M830 - U1327
[45] 4,4′-bis(N,N-diethylamino)-2,2′-bipyridine
Alborés, P
Baraldo, LM
Ibañez, A
Baggio, R
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2004, 60 : O850 - O852
[46] Dimethyl(2,2′:6′,2"-terpyridine-κ3N,N′,N")zinc(II)
Shalumova, Tamila
Tanski, Joseph M.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1325 - U786
[47] Dibromido(2,2′:6′,2"-terpyridine-κ3N,N′,N")zinc(II)
Zhao, Qing-Lan
Li, Guo-Peng
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M693 - U871
[48] Redetermination of bis(2,2′-bipyridine-κ2N,N′)-iodocopper(II) iodide
Liu, Y
Xu, DJ
Wu, JY
Chiang, MY
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : M733 - M734
[49] Tris(2,2′-bipyridine-κ2N,N′)copper(II)bis(tetrafluoridoborate)
Chamayou, Anne-Christine
Biswas, Chaitali
Janiak, Christoph
Ghosh, Ashutosh
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1936 - U1347
[50] Tris(2,2′-bipyridine-κ2N,N′)copper(II) bis(tetrafluoridoborate)
Huang, Wei
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M2254 - U95

← 1 2 3 4 5 →